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Product Name: |
Vanillin |
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Synonym: |
Vanillin cas: 121-33-5: EugenolEP impuritas H. VANILLINE: VANILLIC aldehyde, VANILLIN, vanilla, Vanillinum: Vanilin |
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CAS: |
121-33-5 |
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MF: |
C8H8O3 |
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MW: |
152.15 |
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EINECS: |
204-465-2 |
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Product Categories: |
Aromatica sunt, Intermediates & denique chemicals: Isotope Labeled Fluorure; organicum eget, aldehydes: Bioactive UMP: Building Blocks, C8; Carbonyl Fluorure; Cell Biology: Libera Synthesis: Organic Building Blocks: Pharmacopoeia: Pharmacopoeia AZ, cibum additives, PHARMACEUTICALS, Victus quod pascere Additive: MULTA Donec & intermedia, V, Polyether Antibiotics: analyticae Reagents: analyticae / Citoquinina; per Application: Derivatization Reagents: Derivatization Reagents Bacteria, Bacteria Derivatization Reagents: NUTRICIUM Research: Phytochemicals per fragilis (Cibus / Spice / herb); Vaccinium (Bilberry); officinarum (Ginger): Pasce & cibum additives, Aromata, & aldehydes Vocabulary (suffectus); Quaestiones analyticae, TLC maculata additives Victus & turpis, turpis, Inhibitors |
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Mol File: |
121-33-5.mol |
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Liquescens punctum |
81-83 ° C (Litt.) |
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Ferveret |
CLXX ° mmHg C15 (lit.) |
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density |
1.06 |
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vapor densitatem, |
5.3 (VS caeli) |
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vapor pressura |
> 0.01 mm Aggaei (XXV ° C) |
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potenti |
MMMCVII | VANILLIN |
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refractivam index |
1.4850 (estimate) |
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Fp |
CXLVII ° F |
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temp repono. |
armarium frigidarium |
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solubility |
methanolum: 0.1 g / ml, liquet |
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forma |
crystallinum pulveris |
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pka |
7,396 pkA ± 0.004 (0.00 H2OI = T = ± 1.0 25.0) (PRAEIUDICATUS) |
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color |
Albis vel pallide flavo |
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PH |
4.3 (10g / l, H2O, 20a) |
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aqua Solubility |
X g / L (ºC XXV) |
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sensitivo |
Aeris & LightSensitive |
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Merck Poland |
14,9932 |
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Number JECFA |
889 |
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BRN |
472792 |
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Stabilitatem: |
Firmum. Maydiscolour aspirante lucem. Humorem, sensitivo. Strongoxidizing contra mentem agentium, Sodium peroxide. |
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CAS DataBase Reference |
121-33-5 (CAS DataBase Reference) |
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Quaestiones NIST Reference |
Benzaldehyde,-III-IV-hydroxy methoxy- (121-33-5) |
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Ratio Subcriptio quod substantia EPA |
Vanillin (121-33-5) |
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aleam Codes |
X, XI |
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risk Denunciationes |
22-36 / XXXVII / 38-36 |
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Denunciationes salutem |
XXIV / 25-22-37 / 39-26-36 / XXXVII / XXXIX |
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RIDADR |
UN Consilium MMCMXXIV III / VIII / PG II |
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Germania WGK |
1 |
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RTECS |
YW5775000 |
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Autoignition Temperature |
> CD ° F |
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Capparis |
Ita |
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HazardClass |
3/8 |
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PackingGroup |
II |
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HS Code |
29124100 |
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Ancipitia substantiae Data |
121-33-5 (Malo Periculosam substantias Indicium) |
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Aedes |
LD50 viva apud mures inclusi essent, Guinea porcos: MDLXXX, MCD mg / kg (Jeuner) |
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Flavors: vanillin isedible CONDITIO agens, cum vanilla faba quoque odorem suavitatis, et cupidissimus, milkfragrance, est magni momenti et necessitate rudis materia et cibus additivesindustry, late usus est in omni necessitate ad augendam lac dedit odorem flavor flavoringin cibum, ut crustulam, frigus bibit, scelerisque, candy, tortulas, instantnoodles, panem et tobacco, CONDITIO potione et dentifricium, saponem, stacten in unguentum, glacies crepito, potionibus et aromatibus uterentur ludere in odorem et saporem vitiet. Non enim potest aliquis etiam usus herbam borith, maculata toothpaste, unguentum, Flexilis, plastic, pharmaceuticalproducts. Sic AD FCCIV vexillum. |
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Est AD 0 ~ 10mg / kg (FAO / WHO, MCMXCIV). |
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Potenti (mg / kg) LXIII softdrinks; XCV frigus; Candy CC; CCXX cibus coquitur; classis CXX eu, chewinggum, CCLXX; CMLXX scelerisque, CL accumsan metus; margarine 0.20; syrup330 ~ (XX). |
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Alba needlecrystal cum fragrantiam. Solutum in aqua temporibus CXXV, XX et II temporibus ofethylene glycol XCV% of tempore ethanol, in chloroform posse dissolvi. |
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Properties eget |
Vanillin acharacteristic habet, alba, vanilla, sicut est valde dulcis saporem odorem nostrum. |
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Properties eget |
Alba, crystallineneedles; SUBDULCIS odor. CXXV partes aquae solubiles, in Glycerol partibus XX et II partes XCV% sive spiritus ardens; et ex aethere solutum in chloroform. Combustibilis ab aere obscuritas. |
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Properties eget |
Alba aut crepito, qui acus vel crystallinum pulveris mobilitate ingenii sweettaste sapore et vanilla. |
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res |
Vanillin occurswidely in natura; non est relatus in essential Javacitronella oleum ex (Cymbopogon nardus Rendl.), in quìdem, Peru balsamo simul scidit oiland stercoris columbarum maxime vanilla (Vanilla planifolia, V. tahitensis, pompona V.), coluerunt magis quam XL varietates vanilla, vanillin plantis attrahunt sicut et praesens Glucosum, et vanillin. Referuntur in guava, feyoa fructum, bacae tamnum et asparagus et PORRUM, cinnamo, gingiberi, Scoticis spearmint oleum, nutmeg, rigidas et siliginis panem, butyrum, lac, innitatur et fatty piscis curatus suilla, cervisiam, cognac, whiskeys, sherry, vinum vina rum Cocos, capulus tea roastbarley, popcorn, oatmeal, Cloudberry passionis fructum fabam Tamarind, dillherb et semen tuum frumentum oleum brasii peucedani, elderberry, loquat, Borbonio andTahiti vanilla et pancratium radix. |
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usibus |
Vanillin aflavorant est artificialis seu factum ex synthetica vanilla quæ non possunt ex fromlignin pasce sero pingui sulfite syntheti- et retuli ibi localiter a processionaliter guaiacoland eugenol. et related productum, ethyl vanillin habet tres unum, halftimes CONDITIO in virtute vanillin. et vanillin refers to the ingredient in primaryflavor vanilla, quam adeptus est per extractionem, faba quoque ex thevanilla. vanillin adhibetur, pro vanilla extract, withapplication in glacies crepito, demerita, arte pistoria, ad quas potiones aut 60a CCXX ppm. |
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usibus |
Andanalytical tenui media. |
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usibus |
Pharmaceutic auxilium (saporem). Ut a CONDITIO agens CUPPEDIAE, quas potiones et cibos animalfeeds. Fragance sapor et aromatibus uterentur. Quia tenui synthesis. OfL fonte, dopa. |
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usibus |
Et primarycomponent extract de faba quoque Vanilla. |
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usibus |
Naturaliter ciborum varietate plantarum Vanillin.Occurs intitulatum ut lacus; majorcommercial vanillin natura fons sit faba quoque extract de vanilla. Syntheticallyproduced Lignina-fundatur in-m mole illuc byproduct chartam vel fromguaicol processus. |
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definitio |
ChEBI: A genus of the membrum benzaldehydes de transmigratione, et yl hydroxy substituents atpositions III et IV respectively. |
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productio modos |
Vanillin occursnaturally pluribus essentialis olea et praecipue de siliquis Vanillaplanifolia tahitensis et vanilla. Industrially, vanillin fromlignin paratus est, quod fit ex sulfite produci per erigent papermanufacture. Cum elevatum temperatus ad alcali andpressure Lignina est tractata, a catalyst in conspectu Domini, formare et universa mixtisque ofproducts unde vanillin solum est. Tunc purificatus est Vanillin bysuccessive recrystallizations. |
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compositionem |
Praeterea tovanillin (circiter III%), vanilla continet principiis ceteris odo: vanillin, piperonal, eugenol, glucovanillin, vanillic acidum: Acidum anisic andanisaldehyde. Cum vanillin est consociata cum characteristicfragrance de plant, et non qualis est vanilla faba quoque consociata withthe vanillin contentus. Burbonius faba continent princeps in moles purus vanillin comparedto Tahiti et fabam. |
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Aroma limine values |
DEPREHENSIO: XXIX: ppm bilionem to1.6; recognition: IV: ppm |
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Saporem limine values |
Ppm Tastecharacteristics ad X; suavis, ut typical-vanilla, IBISCUM, cremeae, Alcaloide, caramellic cum pulveream simpliciter. |
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Agrippina Minor aqua Aeris & |
Oxidizes onexposure tardius ad aerem. . Leviter aqua solutum. |
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Reactividad Profile |
Vanillin potest reactviolently cum Br2, HClO4, kalium-tert-butoxide (methyl-tert-benzene NaOH +), (+ T formic acid (NO3) III). . Aldehyde Vanillin est. Aldehydes arereadily Oxidized ad carboxylate acida. Flammabiles et / vel aregenerated toxicus vapores e combinatione cum aldehydes Azo, Diazo componit, dithiocarbamates, nitrides et fortis reducing agentibus. Aldehydes reactwith caeli possunt dare primum peroxo acida, si ad ultimum carboxylate acida. Theseautoxidation rationes profectae sunt activated a lumine, catalyzed oftransition ex sales metallorum et autocatalytic autem (per ea quae per catalyzed thereaction). |
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ignis DISCRIMEN |
Mico punctum notitia forVanillin non funguntur, quamvis hoc probabiliter Vanillin combustibilis ab aere obscuritas. |
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salutem Profile |
Et mediocri toxicus byingestion, intraperitoneal, telae et intravenous routes.Experimental set effectus. Mutationem notitia humana relata. Cum Br2 reactviolently potest, HClO4, kalium-tert-butoxide, tert- chlorobenzene + NaOH, formic acid + thallium nitrate. Corrumpi autem succensa emitsacrid exagitandis fumi odor. Vide etiam aldehydes. |
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Synthesis eget |
Ex vastum (liquor), et lignum pulpam industria; sulfite in solitudinem et extrahitur liquor vanillin cum benzene aftersaturation CO2 est. Et per Vanillin derivednaturally fermentum. |
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storage |
Et lux caeli in humida oxidizesslowly Vanillin affectus. |
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Ratio purificatione |
Crystallize vanillinfrom EtOH aquam et aquea, non autem per destillationem in vacuo. [Beilstein IV1763 VIII.] |
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incompatibilities |
Withacetone esse formatam a coloribus compositis. A practicallyinsoluble compositis, in ethanol praeservatum plasmatus est et GLYCERINUM. |
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Status regulatory |
Gras listed.Included per FDA Inactive Ingredients Database (solutions oris, suspensiones, syrupis, loculos tabulamque lacerto). Nonparenteral medicineslicensed includitur in in UK. Index includitur in Canadian bonus Non medicinalIngredients. |
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et rudis materiae |
Sodium hydroxide -> Hydrochloric acidum -> Sulphuric acidum -> sodium carbonas -> Chloroform -> Fenol -> N, N-Dimethylaniline -> Hexamethylenetetramine -> Calcium hydroxide -> Chloral -> N -Methylaniline -> o-Anisidine -> sulphureo aCIDUM -> Glyoxylic acidum -> Guaiacol -> Eugenol -> Benzenesulfonic acidum -> LIGNOSULFONIC acid calcium sal -> Safrole -> Lignina, ALKALI- -> DIMETHYLANILINE -> vanilla extract -> Ligninsulfonate |
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Praeparatio Products |
Butanol I-III-yl -> (3R, 4s) -1 Benzoyl-3- (I-I-methylethoxy, yl) -4-phenyl-II-azetidinone -> III-o-Methyldopamine hydrochloride-- > iodo-III-4,5-dimethoxybenzaldehyde -> yl-IV-VI-VII-hydroxy, PHENYLCOUMARIN -> Curcumin -> Veratraldehyde -> III-Methoxysalicylaldehyde -> 3,4,5 Trimethoxybenzaldehyde--, >-III-IV-BENZYLOXY METHOXYBENZALDEHYDE -> Capsaicin -> Isovanillin -> S - (-) - Carbidopa -> Methyldopa -> 1,2,4, Trimethoxybenzene -> Diaveridine -> 4 [ (methyl-II-VI-FLUOROBENZYL) OXY] -3-METHOXYBENZALDEHYDE -> dopaminérgico -> 1- (-III-IV-hydroxy methoxyphenyl) -2-NITROETHENE -> formyl-II-IV-tert-Butyl METHOXYPHENYLCARB ONATE, XCIX -> Dimethoxybenzaldehyde, 2,3 -> lemongrass CIL, Indiae occidentalis TYPE -> Bromus-II-IV-VI-formyl, METHOXYPHENYLACETATE -> vanilla extract -> 2,4,5 Trimethoxynitrobenzene-, -> DIBROMO-2,3-IV-V-hydroxy, METHOXYBENZALDEHYDE -> trans-Ferulic acidum ->-III-IV-hydroxy methoxybenzylaminehydrochloride -> V-Bromovanillin -> Dihydroxybenzoic acid, 3,4 -> 4 (II, amino-ETHYL) -2-phenol, yl -> CITRONELLYL propio -> V-Hydroxyvanillin -> Cras interdum sollicitudin ante (3,4-DIMETHOXYPH ENYL) -A-CYANOPROPIONALDEHYDEDIMETHYLACETAL -> CITRONELLYL formate |
