Vanillin

Product Name:

Vanillin

Synonym:

Vanillin cas: 121-33-5: EugenolEP impuritas H. VANILLINE: VANILLIC aldehyde, VANILLIN, vanilla, Vanillinum: Vanilin

CAS:

121-33-5

MF:

C8H8O3

MW:

152.15

EINECS:

204-465-2

Product Categories:

Aromatica sunt, Intermediates & denique chemicals: Isotope Labeled Fluorure; organicum eget, aldehydes: Bioactive UMP: Building Blocks, C8; Carbonyl Fluorure; Cell Biology: Libera Synthesis: Organic Building Blocks: Pharmacopoeia: Pharmacopoeia AZ, cibum additives, PHARMACEUTICALS, Victus quod pascere Additive: MULTA Donec & intermedia, V, Polyether Antibiotics: analyticae Reagents: analyticae / Citoquinina; per Application: Derivatization Reagents: Derivatization Reagents Bacteria, Bacteria Derivatization Reagents: NUTRICIUM Research: Phytochemicals per fragilis (Cibus / Spice / herb); Vaccinium (Bilberry); officinarum (Ginger): Pasce & cibum additives, Aromata, & aldehydes Vocabulary (suffectus); Quaestiones analyticae, TLC maculata additives Victus & turpis, turpis, Inhibitors

Mol File:

121-33-5.mol

Liquescens punctum

81-83 ° C (Litt.)

Ferveret

CLXX ° mmHg C15 (lit.)

density

1.06

vapor densitatem,

5.3 (VS caeli)

vapor pressura

> 0.01 mm Aggaei (XXV ° C)

potenti

MMMCVII | VANILLIN

refractivam index

1.4850 (estimate)

Fp

CXLVII ° F

temp repono.

armarium frigidarium

solubility

methanolum: 0.1 g / ml, liquet

forma

crystallinum pulveris

pka

7,396 pkA ± 0.004 (0.00 H2OI = T = ± 1.0 25.0) (PRAEIUDICATUS)

color

Albis vel pallide flavo

PH

4.3 (10g / l, H2O, 20a)

aqua Solubility

X g / L (ºC XXV)

sensitivo

Aeris & LightSensitive

Merck Poland

14,9932

Number JECFA

889

BRN

472792

Stabilitatem:

Firmum. Maydiscolour aspirante lucem. Humorem, sensitivo. Strongoxidizing contra mentem agentium, Sodium peroxide.

CAS DataBase Reference

121-33-5 (CAS DataBase Reference)

Quaestiones NIST Reference

Benzaldehyde,-III-IV-hydroxy methoxy- (121-33-5)

Ratio Subcriptio quod substantia EPA

Vanillin (121-33-5)

aleam Codes

X, XI

risk Denunciationes

22-36 / XXXVII / 38-36

Denunciationes salutem

XXIV / 25-22-37 / 39-26-36 / XXXVII / XXXIX

RIDADR

UN Consilium MMCMXXIV III / VIII / PG II

Germania WGK

1

RTECS

YW5775000

Autoignition Temperature

> CD ° F

Capparis

Ita

HazardClass

3/8

PackingGroup

II

HS Code

29124100

Ancipitia substantiae Data

121-33-5 (Malo Periculosam substantias Indicium)

Aedes

LD50 viva apud mures inclusi essent, Guinea porcos: MDLXXX, MCD mg / kg (Jeuner)

Actio et usu

Flavors: vanillin isedible CONDITIO agens, cum vanilla faba quoque odorem suavitatis, et cupidissimus, milkfragrance, est magni momenti et necessitate rudis materia et cibus additivesindustry, late usus est in omni necessitate ad augendam lac dedit odorem flavor flavoringin cibum, ut crustulam, frigus bibit, scelerisque, candy, tortulas, instantnoodles, panem et tobacco, CONDITIO potione et dentifricium, saponem, stacten in unguentum, glacies crepito, potionibus et aromatibus uterentur ludere in odorem et saporem vitiet. Non enim potest aliquis etiam usus herbam borith, maculata toothpaste, unguentum, Flexilis, plastic, pharmaceuticalproducts. Sic AD FCCIV vexillum.

Aedes

Est AD 0 ~ 10mg / kg (FAO / WHO, MCMXCIV).
LD50 est 1.58g / kg (rat, per os).
MNL est 1g / kg (rat, per os).
Gras (FDA 182.602000).
Periti secundum Unionis Europaeae Committee in February XXIV, non refert thathigh potionis causa dolores capitis, nausea, vomitus, spiritus difficultas, andeven laedas iecoris, renibus, ergo, quod agitur ut lowerallowed dedit.

uti limitata

Potenti (mg / kg) LXIII softdrinks; XCV frigus; Candy CC; CCXX cibus coquitur; classis CXX eu, chewinggum, CCLXX; CMLXX scelerisque, CL accumsan metus; margarine 0.20; syrup330 ~ (XX).
Secundum praescripta fao / WHO: moles est licita et 70mg / kg forfast cibum infantem de canned cibis, et cereals (MCMXCII).

proprietas eget

Alba needlecrystal cum fragrantiam. Solutum in aqua temporibus CXXV, XX et II temporibus ofethylene glycol XCV% of tempore ethanol, in chloroform posse dissolvi.

Properties eget

Vanillin acharacteristic habet, alba, vanilla, sicut est valde dulcis saporem odorem nostrum.

Properties eget

Alba, crystallineneedles; SUBDULCIS odor. CXXV partes aquae solubiles, in Glycerol partibus XX et II partes XCV% sive spiritus ardens; et ex aethere solutum in chloroform. Combustibilis ab aere obscuritas.

Properties eget

Alba aut crepito, qui acus vel crystallinum pulveris mobilitate ingenii sweettaste sapore et vanilla.

res

Vanillin occurswidely in natura; non est relatus in essential Javacitronella oleum ex (Cymbopogon nardus Rendl.), in quìdem, Peru balsamo simul scidit oiland stercoris columbarum maxime vanilla (Vanilla planifolia, V. tahitensis, pompona V.), coluerunt magis quam XL varietates vanilla, vanillin plantis attrahunt sicut et praesens Glucosum, et vanillin. Referuntur in guava, feyoa fructum, bacae tamnum et asparagus et PORRUM, cinnamo, gingiberi, Scoticis spearmint oleum, nutmeg, rigidas et siliginis panem, butyrum, lac, innitatur et fatty piscis curatus suilla, cervisiam, cognac, whiskeys, sherry, vinum vina rum Cocos, capulus tea roastbarley, popcorn, oatmeal, Cloudberry passionis fructum fabam Tamarind, dillherb et semen tuum frumentum oleum brasii peucedani, elderberry, loquat, Borbonio andTahiti vanilla et pancratium radix.

usibus

Vanillin aflavorant est artificialis seu factum ex synthetica vanilla quæ non possunt ex fromlignin pasce sero pingui sulfite syntheti- et retuli ibi localiter a processionaliter guaiacoland eugenol. et related productum, ethyl vanillin habet tres unum, halftimes CONDITIO in virtute vanillin. et vanillin refers to the ingredient in primaryflavor vanilla, quam adeptus est per extractionem, faba quoque ex thevanilla. vanillin adhibetur, pro vanilla extract, withapplication in glacies crepito, demerita, arte pistoria, ad quas potiones aut 60a CCXX ppm.

usibus

Andanalytical tenui media.

usibus

Pharmaceutic auxilium (saporem). Ut a CONDITIO agens CUPPEDIAE, quas potiones et cibos animalfeeds. Fragance sapor et aromatibus uterentur. Quia tenui synthesis. OfL fonte, dopa.

usibus

Et primarycomponent extract de faba quoque Vanilla.

usibus

Naturaliter ciborum varietate plantarum Vanillin.Occurs intitulatum ut lacus; majorcommercial vanillin natura fons sit faba quoque extract de vanilla. Syntheticallyproduced Lignina-fundatur in-m mole illuc byproduct chartam vel fromguaicol processus.

definitio

ChEBI: A genus of the membrum benzaldehydes de transmigratione, et yl hydroxy substituents atpositions III et IV respectively.

productio modos

Vanillin occursnaturally pluribus essentialis olea et praecipue de siliquis Vanillaplanifolia tahitensis et vanilla. Industrially, vanillin fromlignin paratus est, quod fit ex sulfite produci per erigent papermanufacture. Cum elevatum temperatus ad alcali andpressure Lignina est tractata, a catalyst in conspectu Domini, formare et universa mixtisque ofproducts unde vanillin solum est. Tunc purificatus est Vanillin bysuccessive recrystallizations.
Paratus etiam per Vanillin synthetically condensatio alcali infirmus, guaiacol excessum cum levi acidum glyoxylic locus temperatus. Solutio alcalina Theresultant, quibus III-4-hydroxy acidum methoxymandelic isoxidized sunt in aere, a catalyst in conspectu Domini, et vanillin adeptus est byacidification et simultaneous decarboxylation. Tunc purificatus est Vanillin bysuccessive recrystallizations.

compositionem

Praeterea tovanillin (circiter III%), vanilla continet principiis ceteris odo: vanillin, piperonal, eugenol, glucovanillin, vanillic acidum: Acidum anisic andanisaldehyde. Cum vanillin est consociata cum characteristicfragrance de plant, et non qualis est vanilla faba quoque consociata withthe vanillin contentus. Burbonius faba continent princeps in moles purus vanillin comparedto Tahiti et fabam.

Aroma limine values

DEPREHENSIO: XXIX: ppm bilionem to1.6; recognition: IV: ppm

Saporem limine values

Ppm Tastecharacteristics ad X; suavis, ut typical-vanilla, IBISCUM, cremeae, Alcaloide, caramellic cum pulveream simpliciter.

Agrippina Minor aqua Aeris &

Oxidizes onexposure tardius ad aerem. . Leviter aqua solutum.

Reactividad Profile

Vanillin potest reactviolently cum Br2, HClO4, kalium-tert-butoxide (methyl-tert-benzene NaOH +), (+ T formic acid (NO3) III). . Aldehyde Vanillin est. Aldehydes arereadily Oxidized ad carboxylate acida. Flammabiles et / vel aregenerated toxicus vapores e combinatione cum aldehydes Azo, Diazo componit, dithiocarbamates, nitrides et fortis reducing agentibus. Aldehydes reactwith caeli possunt dare primum peroxo acida, si ad ultimum carboxylate acida. Theseautoxidation rationes profectae sunt activated a lumine, catalyzed oftransition ex sales metallorum et autocatalytic autem (per ea quae per catalyzed thereaction).

ignis DISCRIMEN

Mico punctum notitia forVanillin non funguntur, quamvis hoc probabiliter Vanillin combustibilis ab aere obscuritas.

salutem Profile

Et mediocri toxicus byingestion, intraperitoneal, telae et intravenous routes.Experimental set effectus. Mutationem notitia humana relata. Cum Br2 reactviolently potest, HClO4, kalium-tert-butoxide, tert- chlorobenzene + NaOH, formic acid + thallium nitrate. Corrumpi autem succensa emitsacrid exagitandis fumi odor. Vide etiam aldehydes.

Synthesis eget

Ex vastum (liquor), et lignum pulpam industria; sulfite in solitudinem et extrahitur liquor vanillin cum benzene aftersaturation CO2 est. Et per Vanillin derivednaturally fermentum.

storage

Et lux caeli in humida oxidizesslowly Vanillin affectus.
Solutions de vanillin fuerit dissolutum in ethanol praeservatum cursim in lucem dare ayellow-color, leviter amaritudinem, tasting solutio 6,6a -dihydroxy 5,5â -dimethoxy, 1,1â -biphenyl, 3,3â - dicarbaldehyde. Alkaline solutions alsodecompose cursim reddere brunneis color-solutione. Sed solutions stablefor aliquot menses produci potest addere 0.2% sodium metabisulfite w / v asan antioxidant.
In mole materia debet repono in vase bene clausa, agresti fromlight in a frigus, arida est.

Ratio purificatione

Crystallize vanillinfrom EtOH aquam et aquea, non autem per destillationem in vacuo. [Beilstein IV1763 VIII.]

incompatibilities

Withacetone esse formatam a coloribus compositis. A practicallyinsoluble compositis, in ethanol praeservatum plasmatus est et GLYCERINUM.

Status regulatory

Gras listed.Included per FDA Inactive Ingredients Database (solutions oris, suspensiones, syrupis, loculos tabulamque lacerto). Nonparenteral medicineslicensed includitur in in UK. Index includitur in Canadian bonus Non medicinalIngredients.

et rudis materiae

Sodium hydroxide -> Hydrochloric acidum -> Sulphuric acidum -> sodium carbonas -> Chloroform -> Fenol -> N, N-Dimethylaniline -> Hexamethylenetetramine -> Calcium hydroxide -> Chloral -> N -Methylaniline -> o-Anisidine -> sulphureo aCIDUM -> Glyoxylic acidum -> Guaiacol -> Eugenol -> Benzenesulfonic acidum -> LIGNOSULFONIC acid calcium sal -> Safrole -> Lignina, ALKALI- -> DIMETHYLANILINE -> vanilla extract -> Ligninsulfonate

Praeparatio Products

Butanol I-III-yl -> (3R, 4s) -1 Benzoyl-3- (I-I-methylethoxy, yl) -4-phenyl-II-azetidinone -> III-o-Methyldopamine hydrochloride-- > iodo-III-4,5-dimethoxybenzaldehyde -> yl-IV-VI-VII-hydroxy, PHENYLCOUMARIN -> Curcumin -> Veratraldehyde -> III-Methoxysalicylaldehyde -> 3,4,5 Trimethoxybenzaldehyde--, >-III-IV-BENZYLOXY METHOXYBENZALDEHYDE -> Capsaicin -> Isovanillin -> S - (-) - Carbidopa -> Methyldopa -> 1,2,4, Trimethoxybenzene -> Diaveridine -> 4 [ (methyl-II-VI-FLUOROBENZYL) OXY] -3-METHOXYBENZALDEHYDE -> dopaminérgico -> 1- (-III-IV-hydroxy methoxyphenyl) -2-NITROETHENE -> formyl-II-IV-tert-Butyl METHOXYPHENYLCARB ONATE, XCIX -> Dimethoxybenzaldehyde, 2,3 -> lemongrass CIL, Indiae occidentalis TYPE -> Bromus-II-IV-VI-formyl, METHOXYPHENYLACETATE -> vanilla extract -> 2,4,5 Trimethoxynitrobenzene-, -> DIBROMO-2,3-IV-V-hydroxy, METHOXYBENZALDEHYDE -> trans-Ferulic acidum ->-III-IV-hydroxy methoxybenzylaminehydrochloride -> V-Bromovanillin -> Dihydroxybenzoic acid, 3,4 -> 4 (II, amino-ETHYL) -2-phenol, yl -> CITRONELLYL propio -> V-Hydroxyvanillin -> Cras interdum sollicitudin ante (3,4-DIMETHOXYPH ENYL) -A-CYANOPROPIONALDEHYDEDIMETHYLACETAL -> CITRONELLYL formate