AMBROX DL

Product nomen:

CETALOXAMBROX DL

Synonyma:

Iridiumether;1-b]furan,dodecahydro-3a,6,6,9a-tetramethyl-Naphtho[2;

6,6,9a-tetramethylnaphtho[2,1-b]furan;

DL;DODECAHYDRO-3A,6,6,9A-TETRAMETHYLNAPHTO-(2,1-B)-FURAN;Dod

ecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b] fur;Ambermor;

perhydronaphthofuran

CAS;

3738-00-9

MF:

C16H28O

MW:

236.39

EINECS:

223-118-6

Categoria:

Mol fasciculi:

3738-00-9.mol

punctum liquescens 

75-76°C

fervens 

273.9±8.0°C(Predicta)

density 

0.939 ± 0.06 g/cm3(Predicta)

FEMA 

3471 | 1,5,5,9-TETRAMETHYL-13-OXATRICYCLO(8.3.0.0(4,9)) TRIDECANUM

Odor

ad 10.00 % in dipropylene glycol. aridum nemorosum electri ambergris MOSCHUS dulcis

Odorem Type

electri

JECFA Number

1240

LogP

5.41

EPA Substantia Registry System

Naphtho[2,1-b] furan, dodecahydro-3a,6,6,9a-tetramethyl- (3738-00-9)

3a,6,6,9a-Tetramethyldodecahydronaphtho[2,1-b] furan est autoxidatio crystallina, productus ambrein cum odore ambergris typico. Praeparatum est ex (?)-sclareol, alcohol diterpenum ab extractione plantarum claree sapientium consecutum. Degradatio oxidativa ad lactonam ("sclareolide"), hydrogenationem illius ad diol respondentem, et siccitatibus cedunt tituli compositi.

Eventum

Relatum est in oleum salvium clary.

Praeparatio

Racemica sclareolide praeparari potest per cyclizationem acidi homofarnesici coram SnCl4 sicut catalyst. Puri diastereomeri obtinentur cyclizationem acidorum (E)- et (Z) -4-methyl-6-(2,6,6-trimethylcyclohex-l(2)-enyl)-3- hexen-1-ol, paratae ex 2-methyl-4-(2,6,6-trimethylcyclohex-l(2)-enyl)-2- butenalis [394]. Si mixtura racemica sclareolide in enantiomers resolvitur, oxide etiam obtineri potest per viam syntheticam prorsus.

Definition

ChEBI: Ambronide naphthofuran est.

Synthesis Reference(s)

Synthesis, p. 216, 1983 DOI: 10.1055/s-1983-30287

Nomen commercium

Compositum a sclareolo naturali incipiens: Ambermore, Ambermore-DL, Ambermore-EX (Aromor), Ambrox® Super (Firmenich), Ambroxan® (Kao), Ambroxide (Symrise); composita ab acido homofarnesico derivata: Ambrox® DL (Firmenich); composita ab 2-methyl- 4-(2,6,6-trimethylcyclohex-l(2)enyl)-2-butenala: Cetalox® (Firmenich), Cetalor (Aromor).

Rudis materiae

DIHYDRO CUMINYL ALCOHOL