depictio producti

Methyl dihydrojasmonate Basic informationes

Product nomen:	Methyl dihydrojasmonate
Synonyma:	3-oxo-2-pentyl-cyclopentaneaceticacimethylester;Cyclopentaneaceticacid,3-oxo-2-pentyl-, methylester; hedione; A.K.A. METHYL EPI-DIHYDROJASMONATE;(3-Oxo-2-pentyl-cyclopentyl)-acetic Acidum yl niensis Methyl Dihydrojasmonate (Cis- et trans- mixtisque); MEthyl DIHYDROJASMONATE HC;(2-pentyl-3-oxocyclopentyl) aceticum Acidum yl ester
CAS;	24851-98-7
MF:	C13H22O3
MW:	226.31
EINECS:	246-495-9
Categoria:	Alphabetical Listings, Sapores et odores, sicut odorem eget ad usum in saporem, odorem, et alia medicamenta; Inhibitors, M-N*
Mol fasciculi:	24851-98-7.mol

Methyl dihydrojasmonate Chemical Properties

fervens	110 °C0.2 mm Hg (lit.)
density	0.998 g/mL at 25 °C(lit.)
FEMA	3408 \| METHYL DIHYDROJASMONATE
refractivus index	n20/D 1.459(lit.)
Fp	>230 °F
solubility	H2O: insolubilis
Aqua Solubility	399.8mg/L(25 C)
JECFA Number	1898
Merck	14,6052
InChIKey	KVWWIYGFBYDJQC-GHMZBOCLSA-N
CAS Reference	24851-98-7 (CAS Reference)
NIST Chemia Reference	Acidum cyclopentaneaceticum; 3-oxo-2-pentyl-, methyl niensis (24851-98-7)
EPA Substantia Registry System	Methyl 3-oxo-2-pentyl-cyclopentaneacetate (24851-98-7)

Methyl dihydrojasmonate Salutis Information

Salus Denunciationes	23-24/25
WGK Germania	2
RTECS	GY2453800
HS Code	29183000
Toxicity	LD50 (g/kg): >5 viva voce in mures; > V dermally in cuniculis (Cibi Chem. Toxicol.)

Methyl dihydrojasmonate Ritus et Synthesis

Descriptio	Methyl dihydrojasmonate potentem habet suavem floralem, Aeneanlike, aliquantum fruity odoris. Hoc est odoriferum component in Aenean oleum (Jasminum gradiflorum L.). Praeparari potest ex condensatione 2-pentyl-2-cyclopenten-l-una cum ethylum malonatum, quod sequitur hydrolysim, decarboxylationem, et methylationem.
Chemical Properties	Methyl dihydrojasmonate potentem suavem floralem habet, Aenean-simile, aliquantum fruity odoris. Hoc compositum est odoriferum Aenean oleum (Jasminum gradiflorum L.)
Chemical Properties	Methyl dihydrojasmonate est Aenean odor quod est propinqua yl jasmonate, quod est in Aenean oleo. Methyl dihydrojasmonate fuit idem in tea. Liquor est cum fructu typico, Aenean flore odoris. Methyl dihydrojasmonate praeparatur a Michaele addito acido malonico esters ad 2-pentyl-2-cyclopenten-l-unum, quam sequitur hydrolyfis et decarboxylation consequentis (2-pentyl-3-oxocyclopentyl) malonatae, et esterificatio (acidi 2-pentyl-3-oxocyclopentyli) acetici [304]. 2-pentyl-2-cyclopenten-1-una ab aldol condensatione praeparatur cyclopentanone and valeraldehyde and subsequent isomerization of the " 2- pentylidenecyclopentanone aut Palladium catalyzed decarboxylation of allyl 2-oxo-1-pentylcyclopentanecarboxylata. Dealkoxycarbonylatio malonati etiam directe perfici potest cum aquam in excelso tortor. Methyl dihydrojasmonata memoratae qualitatis constat ex 9 : 1 aequilibrium mixtum ex trans- et cis-isomers. Sed yl cisdihydrojasmonate multo vehementius isomer, cum limen XX temporibus inferior quam trans-isomer. Ideo yl dihydrojasmonate qualitates cis-isomer ditatae sunt etiam venales. Haec "summa-cis" producta sunt liquores hyalinae cum praepotentibus Aenean character.Thedifferent qualitates commerciales contineant diversas pondera, cis-isomer. Summus yl dihydrojasmonate est materia pretiosa in odoribus subtilibus at problemata stabilitate laborat propter suam inclinationem ad isomerize in the aequilibrium mixtum et ideo in aliis unguentariis tantum limitatum usum utilibus. Summus cis yl dihydrojasmonatus produci potest ex aequilibrio mixtionis per speciales artes distillationis in quibus fit per isomerization actio aphronitri. Altitudo methyl dihydrojasmonate cis proportio obtineri etiam potest per hydrogenationem yl dehydrodihydrojasmonati, quod pervium ex 1(2-furyl)-hexanol per rearrangement, isomerization; adherificationem et condensationem cum dimethyl malonatis. Pro aliis syntheticis aditibus stereoselectivis, vide recensionem. Isomers, omnium possibilium, maxime tenet proprium et intensum Aenean odor.Profecto industriae fieri processus ad productionem yl dihydrojasmonate cum magna portione hoc isomer orta est. Processus catalytic hydrogenation de acido cyclopenteneacetico respondente coram ruthenium (II) complexum cum ligandis chiralibus et esterificatione subsequente. Methyl dihydrojasmonate adhibetur in unguentariis ad flores odores; praesertim in Aenean typi.
Praeparatio	Condensatione 2-pentyl-2-cyclopenten-1-una cum ethylo malonato, quam sequitur hydrolysis; decarboxylation et methylation
Gustus limina values	Sapor notae ad 20 ppm: dulce, florum, citrum, fruity et bacca cum tutti-frutti subnotat.
Nomen commercium	Claigeon®, Cepionate® (Nippon Zeon), Hedione®, Hedione®HC (Firmenich), Kharismal® (IFF).