yl Dihydrojasmonate

Product Name:

yl dihydrojasmonate

Synonym:

Oxo-II-III-pentyl cyclopentaneaceticacimethylester: Cyclopentaneaceticacid, II-III-oxo pentyl-, methylester: hedione: CEPIONATEA.K.A. METHYL EPI, DIHYDROJASMONATE (-II-III-Oxo, pentyl cyclopentyl) -aceticacid methyl Esther: Methyl Dihydrojasmonate (Cis- et trans- mixtisque); METHYLDIHYDROJASMONATE C. (Pentyl-II-III-oxocyclopentyl) methyl Esther aceticacid

CAS:

24851-98-7

MF:

C13H22O3

MW:

226.31

EINECS:

246-495-9

Product Categories:

Alphabetical Listings; et Sapor Fragrances, in odorem inflavor eget usu ad quendam odorem et quendam et alius applications, Inhibitors, M, N

Mol File:

24851-98-7.mol

Ferveret

CX C0.2 mmHg ° (lit.)

density

0.998 g / ml at25 ° C (Litt.)

potenti

MMMCDVIII | METHYL DIHYDROJASMONATE

refractivam index

n20 / D 1.459 (lit.)

Fp

> CCXXX ° F

solubility

H2O Prunus: insolubilis

aqua Solubility

399.8mg / Q (ºC XXV)

Number JECFA

1898

Merck Poland

14,6052

InChIKey

KVWWIYGFBYDJQC GHMZBOCLSA-N,

CAS DataBase Reference

24851-98-7 (CAS DataBase Reference)

Quaestiones NIST Reference

Acidum Cyclopentaneacetic, II-III-oxo pentyl-, methyl Esther (24851-98-7)

Ratio Subcriptio quod substantia EPA

Methyl3 oxo-II-pentyl, cyclopentaneacetate (24851-98-7)

Denunciationes salutem

23-24 / XXV

Germania WGK

2

RTECS

GY2453800

HS Code

29183000

Aedes

LD50 (g / kg)> 5orally in redibant, > V dermally cuniculosae Celtiberiae (Cibus Res. Toxicol.)

Description

Methyldihydrojasmonate potens est suavis, floralibus, jasminelike, aliquantum fruityodor. Hoc est argumentum curent in odoriferam oleum Aenean (Jasminum grandiflorum gradiflorumL.). II-II, condensatione pentyl praeparatur, una withethyl malonate cyclopenten l sequerentur hydrolysa, decarboxylation et Methylation.

Properties eget

Methyldihydrojasmonate potens est dulcis-floris, Aenean, ut, aliquantum fruityodor. Hoc est, estque compositis [I] iferous pars ofjasmine oleum (Jasminum grandiflorum gradiflorum L.)

Properties eget

Aenean Methyldihydrojasmonate et odor eius non est propinqua ad esse methyljasmonate, et oleum occurs in Aenean. Yl dihydrojasmonate beenidentified est in tea. Quod est typical cum cerato liquido fruity, Aenean, sicut blossomodor.
Yl dihydrojasmonate est paratus by Michael etiam de malonic acidesters ad II-pentyl-II-cyclopenten-l-one, sequitur hydrolysis anddecarboxylation et inde (II-pentyl-III-oxocyclopentyl) malonate, andesterification est (II-pentyl-III -oxocyclopentyl) acetic acidum [CCCIV]-.2 Pentyl-I-II-cyclopenten, qui paratus est per condensationem per aldol betweencyclopentanone et valeraldehyde et subsequent a isomerization theresulting 2. pentylidenecyclopentanone aut Palladii de catalyzeddecarboxylation allyl I-II-oxo pentylcyclopentanecarboxylates .
Fieri etiam potest ex se Dealkoxycarbonylation malonate withwater eleventur ad temperamentum.
Qualitas de praefatae Methyl dihydrojasmonate IX: 1equilibrium mixtisque, et Cis, de trans- isomers. Sed multo magis est intensive methylcisdihydrojasmonate isomer, cum limina about20 temporibus inferior quam est trans-isomer. Ideo methyldihydrojasmonate dotes opibus partes cis-sunt isomer alsomarketed.
Haec enim magno, colore products Cisa ad humorem maxime commercial powerfuljasmine character.Thedifferent qualitates quae differentamounts Cis, de isomer.
Est hoc magnum materia summus Cis yl dihydrojasmonate fragrancesbut in fine patitur ab stabilitate sortitur debitum problems quod habet ordinem ad isomerize in theequilibrium et mixtisque ergo non est usus in aliis limited perfumeryapplications.
Yl summus Cis dihydrojasmonate potest produci ex aequilibrio in quo arte distillatoria versatissimus mixtureby specialem sodium carbonas et theaction isomerization facit. A princeps proportionem quoque cis yl dihydrojasmonatecan adeptus est per hydrogenation dehydrodihydrojasmonate yl, whichis e regione I (II-furyl) -hexanol per novam commixtionem, isomerization, etherification et condensationem per amino malonate.
Nam altera synthetica Stereoselective facere, videatur recensionem.
De isomers omnia possibilia, et (+) - (1 r ·), -cis isomer mostcharacteristic et intensive habet in se Aenean odor.Therefore, et industrially feasibleprocess ad productionem de yl dihydrojasmonate cum magno portionof isomer hoc est developed. Processus catalytichydrogenation quorum unum est ex substantia correspondentes cyclopenteneacetic Acidum coram ruthenium (II) complexwith CHIRAL ligands esterification et subsequent.
Yl dihydrojasmonate est in unguentariam ad flores, odores in praecipue Aenean types.

Praeparatio

Per condensationem of2 pentyl-II-I-unum-cum-cyclopenten ethyl malonate, sequitur hydrolysis, et decarboxylation methylation

Saporem limine values

Tastecharacteristics ad XX ppm, suavis, floral, citri, fruity, et baca withtutti frutti undernotes.

Nomen

Claigeon & Reg:, & Reg Cepionate (Nippon zéon infundendi), Hedione & Reg:: Hedione Reg & HC (Firmenich), Kharismal & Reg: (IFF).

et rudis materiae

Cyclopentanone -> Valeraldehyde