Product Name: |
Sin Isoamyl |
Synonym: |
Yl I-III-butano: methylbutan--III, III-methylbutanoI:-III-Metil butanolo: alcool amilico: Alcoolisoamylique: alcoolamilico: alcoolisoamylique |
CAS: |
123-51-3 |
MF: |
C5H12O |
MW: |
88.15 |
EINECS: |
204-633-5 |
Mol File: |
123-51-3.mol |
|
Liquescens punctum |
-117 ° F |
Ferveret |
131-132 ° F |
density |
0,809 g / ml at25 ° C (Litt.) |
vapor densitatem, |
III (vs caeli) |
vapor pressura |
II mm Aggaei (XX ° C) |
refractivam index |
n20 / D 1.407 |
potenti |
MMLVII | ISOAMYL ALCOHOL |
Fp |
109.4 ° F |
temp repono. |
regio Flammables |
solubility |
25g / l |
pka |
> XIV (Schwarzenbach et al. MCMXCIII) |
forma |
Liquid |
color |
|
Gravitas specifica |
0.813 (XV / 4A) |
PH |
VII (25g / l, H2O, 20a) |
Odor |
Mitis perdunt suavitatem bibitor, non-residua. |
Odor Limen |
0.0017ppm |
terminus explosive |
1.2-9%, 100a ° F |
aqua Solubility |
XXV g / L (XX ºC) |
Î »max |
Î »: CCLX Amax m, 0,06 |
Merck Poland |
14,5195 |
Number JECFA |
52 |
BRN |
1718835 |
Henrici de assidua legis |
33.1 ° F at XXXVII (Bylaite et al., MMIV) |
patefacio fines |
REL NIOSH: TWA 100ppm (CCCLX mg / m3): ppm IDLH D; OSHA PEL: ppm TWA C; ACGIH TLV: ppm TWA C, CXXV stel ppm (adopted). |
Stabilitatem: |
Firmum. Flammable.Incompatible magnis oxidizing agentia fortis acida, acidum chlorides, acidanhydrides. |
CAS DataBase Reference |
123-51-3 (CAS DataBase Reference) |
Quaestiones NIST Reference |
I-butanol, methyl--III (123-51-3) |
Ratio Subcriptio quod substantia EPA |
Methyl-I-III-butanol (123-51-3) |
aleam Codes |
xII |
risk Denunciationes |
10-20-37-66-20 / R20-XXII / R10 XXII, |
Denunciationes salutem |
46-16 S16- |
RIDADR |
MCV III IR / PG III |
Germania WGK |
1 |
RTECS |
EL5425000 |
Autoignition Temperature |
DCXLIV ° F |
Capparis |
Ita |
HazardClass |
3 |
PackingGroup |
II |
HS Code |
29335995 |
Ancipitia substantiae Data |
123-51-3 (Malo Periculosam substantias Indicium) |
Aedes |
LD50 mures inclusi essent in viva voce, 7.07 ml / kg (Smyth) |
chemicae |
Subhyalina vel pallidus
patet flavo oleum liquidum sit. Apple sublimatum CONDITUS odore et sapore. ignis mollibus
punctum: -117,2 Â ° C. Ferventis punctum: CXXX Â ° C. Density Relativum (d2525): 0.813.
Refractivam index (nD20) 1,4075. Toxicus vapores. Et miscibilia in ethanol praeservatum
aether. Solutum in aqua modice. |
Description |
Vocatus Isoamyl hasa natura sus et effundens odorem proprium saporem. Industrially paravit ex fusel oleum byrectification. |
Properties eget |
Vocatus est Isoamyl afusel oleum, cupam, divido, separo sus et effundens odorem proprium saporem. |
Properties eget |
Amyl alcohols (Pentanols) ut octo isomers. Omnium fomes colore liquido praeter 2,2- isomer in amino-I-propanol, quod est solidum crystallinum. |
Properties eget |
sine colore humor |
Properties eget |
I-III-yl odorthreshold quia caeli sicut relata butanol 0.042 ppm, quam acutae providessome correptionem patefacio ut huius eget. |
Spermatophyta |
Patet, cum a ACUTUS odor colorlessliquid. Odor limine retrahitur a 1.7 ppbv wasreported Yokota et Nagata (MCMXC). |
usibus |
Methyl-I-II-III-butanoland yl I-sunt butanol Northmanni usus est, sive malum pro CONDITIO agentsfor Musa sapientum fixa est vinum. Et quoque mediate et utendum ut mediis solventibus inpharmaceutical chemical products. |
usibus |
Unus autem ex pluribus isomers amyl Isoamylol est pelagus ingredient in Vocatus et oleum productionof Musa sapientum fixa. |
usibus |
Exuberant torcularia quia solvente, dilutum resinam alkaloids, etc .; DOM US vero isoamyl (amyl) Composita, isovaleric acidum, mercurio supernatat fulminare quatinus, pyroxylin, sericum artificialis, lacquers, ACAPNOS pulveris, in Bacteria; Nam dehydrating celloidin solutiones; inmilk adipem ad determinandum. |
definitio |
ChEBI: An hoc est alkylalcohol I-of-butan substituimus per loco ad yl coetus III. |
productio modos |
I-III-butanolis usum methyl sicut menstrua pro unguento delibuti, exuberant torcularia: nisl, ac ceris; in plasticsindustry polyacrylonitrile tuant; quam in fabricandis lacquers, chemicals, et in veneficiis. Et usus est pro CONDITIO et infragrances agentibus. Odio enim orci sed principaliter per contactum dermal andinhalation. |
Praeparatio |
industrially paratus per rectificationem fusel oleum. |
Praeparatio |
Methyl-I-II-III-butanoland yl I-sunt butanol fusel primos olea solitaria a per-products ofethanol a fermento fermentatio. Compositis his etiam sequitur ex thechlorination pentane hydrolysa est. Alius alternative processis oxo per processum quendam, Afrorum ducem belli exercendis armorum officinis et C4 higheralcohols. Et chlorination et oxo processus productio processus est de processibus ad currentcommercial I-III-yl butanol and2-I-butanol yl, sed per processum et oxo hydroformylation isthe reactionem magis aura popularis ierat. Duo sunt enim technologiae principalis processus. Et intulit firstwas amnis ab Ruhrchemie in Germania Exxon 1940sand est fere in in USA referred to as "summus pressura cobalt catalysttechnology". Activae in catalyst est species hydrocarbonyl cobalt, et apressure 200A de CCC requiratur dolor sit ponere statum thecatalyst. In mane 1960s, Crusta commercialized versio moderna legum thecobalt sedibus processus. Hoc technology usus organophosphine ligands, ad minus operating whichallows 30a pressura C ex actione thecatalyst atm, sed inpensa. In technology crusta est prima alcohols usus praesertim theproduction linearibus, cum autem frequens usus est summus pressura cobalttechnology est productio hyphis ramosis alcohols. |
Aroma limine values |
DEPREHENSIO: CCL bilionem ppm ad 4,1 |
Saporem limine values |
gustum ppm habet ad L, fusel, fermentato, fruity, Musa sapientum fixa, aetherias Conniaco |
Communia |
Lexus liquidwith placidam sentire, suffocatio spiritus odoris suavissimi componendum. Rarior aqua solubiles water.Hence aquae supernatet. Asperioribus verbis ipsius fit et vapor. |
Agrippina Minor aqua Aeris & |
Highly flammable.Water solutum. |
Reactividad Profile |
-I-III-Methyl butanolattacks materia plastica [Tractantem Albanica sponsorum tutus, 1980, p. CCXXXVI]. Potassium acid fortes faciat explosions.Mixing consectetuer withconcentrated mixta cum sulphurea aqua aquam acido hypochlorous / carbo tetrachloride solutioncan isoamyl Mercury generare, quod praemium praesertim onexposure caloris solis. Cum CHLORUM non miscentes et isoamylhypochlorites cedere [M CDXCI NFPA, MCMXCI]. -Base catalysed reactiones isocyanatescan fieri per violentiam explosive [Wischmeyer, MCMLXIX]. |
aleam |
Modicus ignis periculum. Vapor est toxicus et irritamentum. Explosive in fines caeli 1.2â IX%. |
salutem DISCRIMEN |
Vaporconcentrations exasperentur oculos altissima tractus respiratorii superioris. Contactwith continua sit causa cutis irritationem. |
eget Reactividad |
cum Reactividad Aqua, nulla reactionem; Reactividad cum Clementine_Vulgate Materias: nullus motus; Stabilitatem Per Onerariis: Stabull; Acidis propter se curat ut medicamentis agens: Non pertinent; Polimerización: non pertinent; Matrix Polimerización: Non pertinent. |
Potentialis expositio |
(Isomer-n): Suspecta reprotoxic aleam: Prima irritamentum (v / o allergic reactionem) (iso-, prima): Possibile periculo formatam secretiori parte natium: Prima irritamentum (v / o allergicreaction) (sec-, primary- activae, et alia isomers) prima irritamentum (v / oallergic reactionem). Uti organi nariae syntheticflavoring synthesis, veneficiis, pede inhibitors; Plastics otherchemicals et facere; ut flotation agente. Et (n-isomer) sit usus est in praeparationem oiladditives, plasticizers, synthetica unguenta, sicut et solvent. |