Geraniol
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Geraniol

Geraniol 's Code est cas 106-24-1

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Geraniol Basic notitia


References Description


Product Name:

Geraniol

Synonym:

Amino-2,6-I-3,7-OCTADIEN, Domine, Domine, I-3,7-amino-2,6-OCTADIENE, amino-3,7-TRANS-I-2,6-OCTADIEN, Domine; TIMTEC, BP ​​SBB007719: TRANS-3,7-amino-I-2,6-OCTADIEN, Domine (2E) -3,7, dimethyl-of-I-2,6-octadien (E) -3,7 -dimethyl-of-I-2,6-octadien (Geraniol) (E) -3,7 Dimethyl-of-I-2,6-octadiex,

CAS:

106-24-1

MF:

C10H18O

MW:

154.25

EINECS:

203-377-1

Mol File:

106-24-1.mol



Donec Geraniol Properties


Liquescens punctum

-15 ° C

Ferveret

229-230 ° C (Litt.)

density

0.879 g / ml at20 ° C (Litt.)

vapor densitatem,

5.31 (vs caeli)

vapor pressura

~ Mm Aggaei 0,2 (XX ° C)

potenti

MMDVII | Geraniol

refractivam index

n20 / D 1.474 (lit.)

Fp

CCXVI ° F

temp repono.

2-8 ° F

solubility

aqua: soluble0.1g / Lat XXV ° F

forma

Liquid

pka

14.45 ± 0,10 (Praedicta)

Gravitas specifica

0.878ï½ 0.885 (XX / 4A)

color

Patet sine colore flavo topale

aqua Solubility

PRACTICALLYINSOLUBLE

Number JECFA

1223

Merck Poland

14,4403

BRN

1722456

Stabilitatem:

Firmum. Combustible.Incompatible magnis oxidizing agentium.

InChIKey

GLZPCOQZEFWAFX JXMROGBWSA-N,

CAS DataBase Reference

106-24-1 (CAS DataBase Reference)

Quaestiones NIST Reference

Octadien-of-I-2,6, 3,7-amino - (E) - (106-24-1)

Ratio Subcriptio quod substantia EPA

trans-Geraniol (106-24-1)


Safety Geraniol Information


aleam Codes

XI

risk Denunciationes

XXXVI / XXXVII / 38-43-41-36-52 / 53-38

Denunciationes salutem

26-36-24 / 25-36 / 37-61-36 / XXXVII / XXXIX

RIDADR

UN1230 - III classis -PG II - Methanol, solution

Germania WGK

1

RTECS

RG5830000

Nota aleam

Simplex

Capparis

Ita

HS Code

29052900

Ancipitia substantiae Data

106-24-1 (Malo Periculosam substantias Indicium)


Synthesis Geraniol Et Usu


Description

Geraniol est kindof monoterpenoid tum arcu. Hoc est maxime enim praecessit in plant suchas rosa olea oleum, oleum palmarosa et oleum citronella. Potest etiam invenitur, ut geraniums et inplants lemongrass. Hoc est, quasi rosa odor unguentorum tum istherefore in plures species saporum, ut persici, RUBUS IDAEUS, grapefruit, pupillam rubrum, pruna, calcem, aureus, CITREA et applicationem blueberry.Another Maior autem est usus quasi Geraniol effectiveplant secundum esse, quia curatio insect abhorrens culicibus, domus fugit, stableflies, terrae proturbabuntur ignis formicae farris, et sola stella ricini et pulices. In alia manu, odore etiam potest attrahunt apes.

Greek New

https://en.wikipedia.org/wiki/Geraniolhttps://pubchem.ncbi.nlm.nih.gov/compound/geraniol#section=Top

Description

Geraniol acharacteristic est, quasi rosa odor. Geraniol parari potest ab his in fractionaldistillation dives in essentialis olea Geraniol aut syntheticallyfrom myrcene; commercial Geraniol non possunt statui secundum itsalcohol contentus, quasi frequentissima ex impuris, quae maxime in natura bibitor (nerol, citronellol, tetrahydrogeraniol). Fungi-Gas maybe utile arte usus est determinare de Geraniol contentus per uber.

Properties eget

Velut rosa odor, et habet Geraniol acharacteristic varia physica constantes ad variouscommercial products, fretus in Geraniol totalis contentus; specifc gravityand refractivam index sit aignum qua puritate productCommercial Geraniol non classifed secundum Vocatus contentus: asmost de recurrentes ex impuris, quae bibitor in natura (nerol, citronellol, tetrahydrogeraniol) Spermatophyta techniques utiliter usus todetermine in gera- niol contentus per uber.

Properties eget

Geraniol terpene-occurs innearly omnia continet essentialis olea, et saepe continet oleum in ester.Palmarosa 70a LXXXV% Geraniol; Geranium unguento delibuti surrexit alsocontain copiosissimum. Geraniol sine colore est ius, cum floralibus, resurrexit, sicut odoris suavissimi componendum.
Cum Geraniol est Herpesvirus hominis; alcohole unsaturated ancipites utrimque, hoc contingit ex anumber profectae sunt, ita ut et novam commixtionem cyclization. Permutandis attrahunt coram aeris catalysts citronellal cedit. In praesentia ofmineral acida, suus cyclizes formare monocyclic terpene hydrocarbonum, cyclogeraniol quod si adeptus est hydroxy munus suscepit me. Partialhydrogenation citronellol conducit atque perfectum reddit doublebonds hydrogenation de l-3,7-o dimethyloctan (tetrahydrogeraniol). Ut ex Citral beobtained Geraniol per catalytic dehydrogenation aut oxidatio. Geranylesters esterification praeparentur.
Maxime saepe usus est ex odore Geraniol Labiatae materiae. Itcan esse in floral compositio quod resurrexit, non sicut discolorsoaps. In flavor compositiones, Geraniol est in modicis toaccentuate citri notas. Hoc est momenti medium ad manufactureof geranyl esters, citronellol et Citral.

Properties eget

odor rosarum fluidi Cheilocystidia paleyellow

res

In praesentia ofgeraniol in natura est relatus in magis quam CLX essentialis olea, Eucalyptus, lemongrass, Taprobanae, et Java citronella, tuberose, quercu MOSCHUS, vel nuces, champaca, Ylang, Ylang, clavae muscatam comedit, sassafras, Cayenne Bois-de-Rose, Acaciafarnesiana, geramium sclareiam extinguere, & aculeo, & lavandin, casia, Aenean, coriandrum, DAUCUS, murrae, eucalyptus, calcem, mandarin Petitgrain, bergamotpetitgrain: bergamot, CITREA, aurantiaco et alii in essentialis olea ofpalmarosa et Cymbopogon winterianus quae sunt suprema ordinis Geraniol ( proxime LXXX ad XCV%) Item nuntiavit in numerosis aliis fontibus comprehendo pomum suci, citri excorio unguentum et sanguinem, bilberry, quadrupedibus, aliud sapere, guava, papaya, cinnamo, gingiberi, frumentum mentham, oleum, sinapis, nutmeg, clavae lac, capulus , tea, cupam, mel, fructus passion, pruna, fungos, mango, starfruit, amomi, et folium, coriandrum seminibus, litchi, Ocimum basilicum, frondes myrti folium, Ros maris sclareiam sapiens, chamaemelon et sapientem Hispanica oleum

usibus

Geraniol exstant summarium adhibetur attrahunt animal repellant. Et factum est in summa a et A ofAngelicoin Herecinone J, quod collagen, adductus plateletaggregation inhibere.

usibus

Plant, herbivore Saccharum adductus esset uti Geraniol infeild iudicium de volatiles asattractants insects.It esset utile putant ad evaluate thetumor, suppressive potentia isoprenoids in vitro et in vivo.

usibus

Tonicum produxi Geraniol isperfuming et proprietatibus. Hoc primarium est apud manyessential unguento delibuti, inter citronella, casia, lemongrass, aurantiaco flore et Ylang, Ylang.

definitio

ChEBI: Amonoterpenoid prenyl constans ex duabus iunctum est coniunctum capite, cauda-hydroxy andfunctionalised cum coetus ad sua cauda finem.

Praeparatio

In productione Geraniol et commodum routefor nerol hydrogenation ofcitral constat quod multa in medium quasi in Vitaminum A. synthesisof eu magna processus ergo forproducing Geraniol succrevit. Currently, plus quam illa sunt, usque isolationfrom essentialis olea. Nihilominus tamen est aliquid Geraniol olea solitaria fromessential unguentariam ad proposita.
I) absque essentialis olea: Geraniol enim dum tangit ab citronella oilsand palmarosa oleum. Fractus distillatoria versatissimus est, exempli gratia, Javacitronella oleum (si opus cum saponificationis de praesenti esters) concedit ramenta de quibus LX% Geraniol, tum citronellol andsesquiterpenes. Aproductwith altiorem Geraniol contentus, leniter differentodor qualis in fine est usus fit per fractionatingpalmarosa oleum suavitatis suæ post saponificationis de geranyl esters.
II) synthesis de dictos isto, pinene: pyrolysis autem eos dictos isto, pinene cedit myrcene quae isconverted in mixtisque magis atque geranyl, neryl et linalylchloride per addition of hydrogenii chloride coram exiguis ofcatalyst, exempli gratia aeris (I) chloride organicum ammoniumsalt et quaternario comprehenditur. Post remotionem de catalyst, Radiorum Permixtionem portavit; et sodiumacetate coram NITROGENIUM in basi (exampla: triethylamine) andconverted ad geranyl acetate, neryl acetate, et moles parva linalylacetate.
Quod fracta sit adeptus, post distillatoria versatissimus Geraniol saponificationis de theresulting alcohols. III) synthesis de linalool: A% XCVI pura per isomerization geraniolprepared synthetica quae ex linalool facti sunt quasi commercium available.Orthovanadates catalysts, reddere> XC% de cede ageraniolâ nerol mixtisque. Et tandem adeptus est, princeps puritatem Geraniol byfractional distillation. Aliquantum availablegeraniol ad commercium est mutatio ad processus produci: linalool adeptus est in LXV% de puritate circiter Î ± -pinene linalyl borates convertitur in hominem prius quam Ordinariorum coetus aliter quam catalysts ad attrahunt coram vanadates geranyl et neryl borates. Thealcohols invenit hydrolysa esters.
IV) synthesis de Citral: Citral est valde nuper venerat ad producedpetrochemically in maxima quantitate, tamque promptum est hydrogenation citralhas facti parricidii gratia et ipsum oeconomica productio ex Geraniol. A highselectivity hoc reactionem potest esse in usum specialem effectum catalysts [CVI] reactionem aut specialis ars.

Aroma limine values

Fungi, ut 75ppb IV.

Saporem limine values

Ppm Tastecharacteristics ad X: foral dulcis rosa, citri et fruity, waxynuances.

Communia

Paleyellow pinguis umor rosa suavis est sine colore et odore.

Reactividad Profile

An unsaturatedaliphatic hydrocarbon et arcu. Flammabiles et / vel toxicus vapores ad alcohols alcali aregenerated ex mixtura quaedam metalla transcurrit, nitrides, andstrong reducing agentibus. Et cum gravissimo oxoacids carboxylic formesters plus aqua acida. MORSUS agentibus et convertam eos ad aldehydes ketones.Alcohols sistere tam debilis et infirma basi acidum mores. Ut initiarent thepolymerization de isocyanates et epoxides.

Research anticancer

Satus fromantitumor cell operatio contra aliquot lineas et per comprehensionem attheG0 occurrentium / G1 cell augmentum cycle humiliat et reapse id est apoptosis, ut ab hac moleculewasfound mevalonic exolvuntur enzyme. Ofprenylation ducit ad inhibicionis supprimere ofproteins DNA synthesis et thesuppression III-of-III-hydroxy methylglutaryl-Salmo (HMG-Salmo) ducit in stagnum andthus mevalonate reductionof in fines isoprenylation dapibus. In sameway est, Reductio onerum regitur eu biodisponibilitywas (Pattanayak et al. MMIX, gens et al. MMXII, Dahham et al.2016).

salutem Profile

Venenum byintravenous iter itineris. Et mediocri toxicus per ingestion, fit, andintramuscular partibus. A gravibus irritationem cutis hominum. Carros SAac. Simul emittuntur, exagitandis acres quoque illum corrumpi Whenheated fumo nasci noscantur.

Synthesis eget

Ab his dives in essentialis olea per fractionaldistillation Geraniol aut syntheticallyfrom myrcene.

Ratio purificatione

Fungi Purify Geraniol byascending aut Angiospermae in laminas ofkieselguhr cum acetone G / aqua / liquidae paraffin (CXXX: LXX: I) ut salvi system.Hexane / ethyl acetate (I, IV) et idoneam. Et aliquid in utensilia ejus, ex GLC asilicone in columna tractata ex Carbowax 20M (X%) de Chromosorb W (reticulum 60-80). [1969. CDXCIX Porter Pure Appl Cham XX] repones intra ianuas plenam, intime sealedcontainers et custodiat in a frigus lux. Quod habeat suavitatem odoris. [S p681: Beilstein 2277. II I]


Rudis materia et Products Geraniol Praeparatio


et rudis materiae

Calcium chloride -> Citral -> Linalool -> Citronellol -> NEROL -> eucalyptus oleum Citriodara -> Collatio sodium -> oleum Citronella -> Myrcene

Praeparatio Products

Citral -> Citronellol -> Citronellal -> NEROL -> amino-3,7-VII-OCTEN-I-L -> Geranyl acetate -> GERANYL BUTYRATE -> Geranyl formate -> potenti 2510- -> amino-I-3,7-OCTANOL -> 2,4,5 TRIMETHYLANILINE,


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