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Ethyl formate Basic informationes

Product nomen:	Ethyl formate
Synonyma:	mrowczanetylu; mrowczanetylu (politura); ETHYL NATURALIS, ETHYL FORMA 97+% FCC; FORMA ETHYL, VEXILLUM AD GC, ETHYL FORMA PARS GRADUS XCVII%; EthylFormateForSynthesis, Ethyl formate (technical)
CAS;	109-94-4
MF:	C3H6O2
MW:	74.08
EINECS:	203-721-0
Categoria:	Organica; Analytica Chemiae, Organic synthesin: Solvents pro HPLC & Spectrophotometry, Solvents pro Spectrophotometry
Mol fasciculi:	109-94-4.mol

Ethyl formate Chemical Properties

punctum liquescens	−80 °C(lit.)
fervens	52-54 °C(lit.)
density	0.921 g/mL at 20 °C(lit.)
vapor density	2.5 (vs. aere);
vapor pressura	15.16 psi (55 °C)
refractivus index	n20/D 1.359(lit.)
FEMA	2434 \| ETHYL FORMATA
Fp	7 °F
repono temp.	Flammabiles area
solubility	Miscible cum alcohol, benzene, et aether (Hawley, 1981)
forma	Liquid
color	Patet
Odor	Characteristic; amoenus aromaticus.
odor Limen	2.7ppm
explosive modum	16%
Aqua Solubility	11 g/100 mL (18 C)
Sensitiva	umor Sensitivus
Merck	14,3807
JECFA Number	26
BRN	906769
Lex Henrici Constant	0.097(x 10-3 atm?m3/mol) at 5.00 °C, 0.13 at 10.00 °C, 0.17 at 15.00 °C, 0.23 at 20.00 °C, 0.29 at 25.00 °C (columna detracta-UV, Kutsuna et al., 2005)
Patefacio fines	TLV-TWA 100 ppm (～300 mg/m3) (ACGIH, MSHA, OSHA); IDLH 8000 ppm (NIOSH).
Stabilitas:	Stabulum. Maxime fomes. Sit formare mixturae explosive cum aere. Nota low mico punctum and wide fines explosive. Fortis oxidizing agentibus repugnat, fortis bases, acida valida, nitrates.
InChIKey	WBJINCZRORDGAQ-UHFFFAOYSA-N
CAS Reference	109-94-4 (CAS Reference)
NIST Chemia Reference	Acidum formicum, ethyl niensis (109-94-4)
EPA Substantia Registry System	Ethyl formate (109-94-4)

Ethyl formate Safety Information

Periculum Codes	F,Xn
Periculum Denunciationes	11-20/22-36/37
Salus Denunciationes	9-16-24-26-33
RIDADR	UN 1190 3/PG 2
WGK Germania	1
RTECS	LQ8400000
Autoignition Temperature	84 °F
TSCA	Ita
HazardClass	3
PackingGroup	II
HS Code	29151300
Ancipitia substantiae Data	109-94-4 (Ancipitium substantiarum Data)
Toxicity	LD50 viva voce in muribus: 4.29 g/kg (Smyth)

Ethyl formate Ritus et Synthesis

Chemical Properties	Formate Ethyl occurs late in fructibus. Est humor leviter pungens, fructuosus, aethereus odoris, et in saporibus fructiferis adhibetur.
Chemical Properties	Ethyl formate habet a proprium, odoris acri similis ethyl acetate et simile pineapple et modice amarum. Renunciatum est etiam habere a rum-ut odoris. Ester leviter solutum in aqua (partes 9/100 ante 18 °C) cum compositione graduali in acidum formic et ethanolum; miscibile est ethanol, aether et acetone (HSDB, 2013), nec non in benzene.
Corporalis proprietatibus	Hyalina, liquet liquore iucundo, fructuoso odore. Odorem limine retrahitur 2.7 ppmv a Nagata et Takeuchi relata (1990).
usus	Saporem for lemonades et essentiae; ad fabrica* rum artificialium et armac- rum; etiam ut solvens nitrocellulosum; ut fungicide et larvicida pro tabaci; frugum, fructuum aridae, etc.; in organicis synthesibus.
usus	Ethyl formate est solvendo usus est; sicut fomes pro lemonades et essentiarum; et sicut afungicide et larvicida pro frugum, fructibus siccis, tabaci, et sic porro.
Definition	Chebi: A formate niensis ex condensatione formali acidi formic cum ethanol.
Productio Methodi	Ethyl formate est factorum per esterficationem acidi formici et ethanoli coram Acidum sulphuricum et per distillationem acetatis ethyi et formic Acidum in conspectu acidi sulphurici.
Aroma limina values	Deprehensio: 17 ppm
Gustus limina values	Sapor notae ad 60 ppm: dulce, chemicum, nitidum, recens, fructiferum litt.
General Description	Patet hyalina liquore suavi odore. Flash point -4°F. Minus densa quam aqua. Vapores aere gravior.
Aer & aqua Reactiones	Magnopere fomes. Solutum in aqua. Tarde resolutum ab aqua ad acidum formic, corrosivum materia et alcohol ethyla, alius liquor fomes.
Ignis Discrimen	Ignis mores: Vapor est gravior quam aer et iter longum spatium ad fontem ignitio et mico retortis.
Chemical Reactivity	Reactividad cum aqua nulla reactio; Reactividad cum Materiis Communibus: Nulla reactio; Stabilitas Per Transport: Stabulum; Agentia pro acidis et causticis: Not pertineret; Polymerization: Not pertinent; Inhibitor Polymerizationis: Not pertineant.
Usus agriculturae	Fumigant; Insecticida: fumigans, praesertim in arido fructu, etiam ut a . solvendo pro nitrate celluloso et acetate et in productione synthetica sapores. Non currently descripserunt ad usum agriculturae in EU terris et US in Australia et sunt LXIII global instructus.
salus Profile	Mediocriter toxicus per ingestion et telae itinera. Mddly toxicus per contactum cutis et inspiratio. Inspiratio vehemens irritamentum in homines. Pellis et oculus irritamentum. Dubium carcinogenum cum notitia tumorigenica experimentali. Magnopere fomes liquoris. Periculosum est valde periculosum ignis et explosionis aleam expositus calor, flamma, oxilzers. Ad ignem pugnare, Vocatus uti spuma, imbre, caligo, siccus chemica. In compositione calefacta emittit fumum acrem et vexo fumus. Vide etiam ESTERS.
vastum Dispositione	Imbre in fornacem permixtionem cum fomes solvendo

Ethyl formate Praeparatio Products Et Rudis Materiae

Praeparatio Products

2-Aminopyrimidine-5-carbonitrile-->4-Chloropyridine-3-carboxaldehyde-->4-METHOXY-3-BUTEN-2-ONE-->2-(TRIFLUOROMETHYL)PYRIMIDIN-4-AMINE-->METHYL. 3-AMINO-6-METHYLTHIOPHENO[2,3-B]PYRIDINE-2-CARBOXYLATUM-->7-Aminoisoquinoline-->6-Methyl-1H-pyrazolo[3,4-b]pyridinum-3-amine-->5-Acetamidomethyl-4-Amino-2-Methyl pyrimidine-->2-AMINO-4-METHYLOXAZOLE-->5-BROMO-4-HYDROXY-2-METHYLPYRIMIDINE-->THIAMIN chloride--> AMITRAZ METABOLITE HYDROCHLORIDE-->ACIDA TROPICA-->4-CHLORO-2-(TRIFLUOROMETHYL)PYRIMIDINE. 3-amino-4-phenylthiophene-2-carboxylato-->3-cyano-6-methyl-2(1H)-pyridinone->N-Methylformamide-->3,4-DIHYDROISOQUINOLINE-->7-NITRO-3,4-DIHYDROISOQUINOXYLIC-->2-AMINO-CYRIMI-->2-AMINO-PYRIMI-->3,4-DIHYDROISOQUINOLINE-->7-NITRO-III,4-DIHYDROISOQUINOLINE-->2-AMINO-CYRIMI-->2 ACIDUM ETHYL ESTER-->4,5,6-TRIAMINOPYRIMIDINE-->2-CHLORO-6-METHYL-3-PYRIDINE-PYRIDINUM-->1H-1,2,3-Triazolo[4,5-d]pyrimidin-7-amine-->Ninhydrin hydratum-->4-METHYL-PYRIMID. HYDROCHLORIDE-->1-(PHENYLSULFONYL)-1H-INDOLE-2-CARBALDEHYDE-->A-(HYDROXYMETHYL) BENZENACETIC ACIDUM METHYL ESTER-->4-Hydroxy-2-(trifluoromethyl)pyrimidine-->4-chloro-5-fluoropyrimidine-->1-Methyl-2-imidazolecarboxaldehyde-->5-N-PROPYLURACIL-->5-PROPYL-2-THIO URACIL-->4-HYDROXY-2-METHYLPYRIMIDINE-->4,5-DIBROMOTHIOPHENE-II-CARBOXALDEHYDE-->7-BROMOISOQUINOLINI-->4-CHLORO-I-ETHYLI-3-METHYL-1H-PYRAZOLE-5-CARBOXYLICI. ACID ETHYL ESTER-->α-Dimethoxymethyl-methoxypropionitrile-->EPOSTANE-->alpha, alpha-diphenyl-L-prolinol-->1,1-Diethoxy-3,7-dimethylocta-2,6-diene

Rudis materiae

Etanol-->Acidum formic-->Calcium chloridum-->Aluminium chloridum hexahydratum

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