Product Name: |
dimethyl sulfide |
Synonym: |
Sulfide amino (XCIX%, HyDry: ppm Waterâ ¤50 (KF a)); sulfide amino (XCIX%, HyDry cum molecularsieves: ppm Waterâ ¤50 (KF a)); fide; methanethiomethane: MethylMonosulfide: methylmonosulfide: Sulfide , methyl-: Sulfurede methyle |
CAS: |
75-18-3 |
MF: |
C2H6S |
MW: |
62.13 |
EINECS: |
200-846-2 |
Product Categories: |
Sulfides flavors; Allium sativum (Allium cepa); Allium sativum (Allium sativum); Building Blocks: Libera Synthesis, NUTRICIUM Research: Organic Building Blocks: Phytochemicals per fragilis (Cibus / Spice / herb); Sulfides / Disulfides: sulphur componit, Bioactive Parvus Molecules; cell Spider-SUFFODIO DY, Suspendisse vitrum utres, Organics, sulfide LaudaBQLig: Reagent, Utres solvente, solvente packaging Options: Solvents: solvent |
Mol File: |
75-18-3.mol |
|
Liquescens punctum |
XCVIII Â ° C (Litt.) |
Ferveret |
XXXVIII ° C (Litt.) |
density |
0.846 g / ml at25 ° C (Litt.) |
vapor densitatem, |
2.1 (vs caeli) |
vapor pressura |
26.24 psi (LV ° C) |
potenti |
MMDCCXLVI | METHYL sulfide |
refractivam index |
n20 / D 1.435 (lit.) |
Fp |
XXXIV Â ° F |
temp repono. |
2-8 ° F |
solubility |
Miscible withalcohols, aetheres, esters, ketones, aliphaticorum et aromaticorum miscible cum hydrocarbons.Slightly |
forma |
Liquid |
color |
patet hyalinae |
Gravitas specifica |
0.849 (XX / 4A) |
Odor |
XVII, diffundatur, disconveniens; taetras esse. |
Odor Limen |
0.003ppm |
terminus explosive |
2.2-19.7% (V) |
Merck Poland |
14,6123 |
Number JECFA |
452 |
BRN |
1696847 |
Stabilitatem: |
Firmum. Fortis Incompatiblewith oxidizing agentium. Altus flammabilia - nota ferveret humilis, punctum lowflash et wide CREPITUS fines. Quae mixta cum aere potentiallyexplosive. Simul acri oxidizing agentium. Usus In UK instituta byLPG MCMLXXVIII Ordinationibus Secundum HSE regere nota CS17. |
InChIKey |
QMMFVYPAHWMCMS UHFFFAOYSA-N, |
CAS DataBase Reference |
75-18-3 (CAS DataBase Reference) |
Quaestiones NIST Reference |
Dimethylsulfide (75-18-3) |
Ratio Subcriptio quod substantia EPA |
Dimethylsulfide (75-18-3) |
aleam Codes |
F, X, XI |
risk Denunciationes |
11-22-37 / 38-41-36 |
Denunciationes salutem |
7-9-16-29-33-36 / 39-26 |
RIDADR |
III IR MCLXIV / PG II |
Germania WGK |
1 |
RTECS |
PV5075000 |
F |
13 |
Autoignition Temperature |
CDII ° F |
Capparis |
Ita |
HS Code |
XCVIII XC MMCMXXX |
HazardClass |
3 |
PackingGroup |
II |
Ancipitia substantiae Data |
75-18-3 (Malo Periculosam substantias Indicium) |
Aedes |
LD50 viva voce inRabbit: DXXXV mg / kg LD50 dermal Materiae> (V) mg / kg |
Description |
Hasan in Mesopotamiam Bactriamve Methyl sulfide iniucundum odor in ut cabbage- sicut etiam armoraciorum. Potest esse toleratedas est holus viride nota nimis humilis gradus solum (0.1 - 3.0 ppm). Ut per reactionem beproduced potassium chloride sulfide et yl in methanolsolution; yl de kalium et kalium sulfate sulfide. |
Properties eget |
Hasan in Mesopotamiam Bactriamve Methyl sulfide insaniam inciderunt insuavis odoris armoraciorum, brassica-similis. Potest esse toleratedas est holus viride nota nimis humilis gradus solum (0.1 ad 3.0 ppm |
Properties eget |
patet colorlessliquid |
usibus |
Sulfiding agente. |
definitio |
ChEBI: A methylsulfide in quibus substitui sulphuris athomo moto yl duabus turmis regredior. Quodam zoophytorum sistens isproduced est naturale. |
Praeparatio |
Yl chloride solutio in methanolum et per reactionem ofpotassium sulfide, potassiummethyl tuum invadant! sulfate et de [I] sium sulfide |
Aroma limine values |
DEPREHENSIO: 0.3 ad 10ppb. Notas odor ad 0,5%, sulfureous, amino sulfide, cremeo, lycopersiciSusceptibility, circum piscosos, PECTEN, fruity, et baca vegetabilis interdum induentia |
Saporem limine values |
Tastecharacteristics V ad I ad ppm, sulfureous vegetativum lycopersiciSusceptibility, suavis, creamedcorn, frumentum et asparagus et dairy creaminess mintyafternote et modicus, alliaceous. |
Communia |
Patet colore coloratum fluidi tostraw tetri odoris. Minus mico punctum 0 esse F.Less densa, leviter quam aqua SOLUBILIS in aqua. Vapores thanair graviora. |
Agrippina Minor aqua Aeris & |
Flammable.Slightly altus aqua solutum. |
Reactividad Profile |
Organosulfides, suchas Dimethyl selenide sunt acida repugnent, et Azo Diazo composita halocarbons, isocyanates, aldehydes, alcali metalla nitrides, hydrides, reducendo fortis andother agentium. Agrippina Minor faciunt calorem in multis casibus cum his materiae generate hydrogenii Gas. Multi ex illis composita sint liberare in compositione vel hydrogensulfide reactionem cum acidum. Dimethyl sulfide rapidlydecomposes dibenzoyl explosively peroxide in absentia menstruis [J. Org.Chem., MCMLXXII, XXXVII, MMDCCCLXXXV]. A xenon difluorideexplosively ad ambientium, sulfide et putrescit tentat [J, Cham Soc., MCMLXXXIV, MMDCCCXXVII]. Doctrina Novae Hierosolymae ofDimethyl sulfide et oxygeni ad CCX is explosive et super F [Atmos.Environ., MCMLXVII, I, 491-497]. A CREPITUS occurrit moratus est in acidum nitricum systemcontaining, Dimethyl sulfide, et I, IV, dioxane, et cum coolingwith Liquid [Sci. Abs., MCMLXXII, LXXVI, (XIII)DXV]. |
salutem DISCRIMEN |
Superna inspiratione causesmoderate respiratorii irritatio. Picis liquidae contactus cum alieni stimulos eyescauses moderari. Repetita cutis contactus cum eliciunt, ut olea andresult in ira exacerbarentur animi. Pisces et irritatio causatur ex ore andstomach nauseam. |
eget Reactividad |
Reactividad withWater: non reactionem, Reactividad cum Clementine_Vulgate Materias: non reactionem, StabilityDuring Onerariis: Stabull; Acidis propter se curat ut medicamentis agens: Notpertinent; Polimerización: non pertinent; Matrix Polimerización: Notpertinent. |
salutem Profile |
Byinhalation venenum. Et mediocri toxicus per ingestion. A cute et gravibus oculis irritamentum. Discrimen flammam ignis calor expositae avery periculosa. Et calor flammae vapor est patere, cum in theform explosive. Possunt reflecti fortiter withoxidizing materiae. Pugnare ignis usum CO2 sicco eget. Incensus et Sox todecomposition emittit maxime noxia fumositates dissiliunt. Vide alsoSULFIDES. |
Ratio purificatione |
Purify dimethylsulfide via ad illud Aggaei I (II) chloride solutio universa iuxta illud Aggaei I molem continuatione (II) Cl2 in1250mL de EtOH et tardius addere ferventis ius bibitor solutionem Me2S togive Ratio enim II (CH3) 2S.3HgCl2. Postquam autem recrystallisation thecomplex assidue ad liquescens punctum, qui universa 500g de 250ml concHCl in equis auolant Romam 750ml aquae. Selenide separatur et lauari aqua et driedwith CaCl2 CaSO4. Denique non reducere pressura generatur per sublimationem in fromsodium. Cautum putamus (t vapor agentibus cucullo) propter veryUNPLEASANT odor ejus. [Beilstein I II 1275] |
et rudis materiae |
Dimethyl sulfate -> disulphide Carbon -> aluminium oxide -> consectetuer sulfide -> Natrium thiomethoxide -> Lignina, ALKALI -> SIGNUM anion - SULFATE |
Praeparatio Products |
Sulfoxide amino -> Dimethoate -> III-FURANMETHANOL -> ETHYL FUROATE-III -> Arachnida, yl -> Ketorolac -> Domine, Domine, DimethylS, methylcarbamoylmethyl phosphorothioate -> Malathion -> Fluorescent brightener CLXXXV -> Ethyl 5. [3. (4.6-II-y-dimethoxypyrimidyl) ureido] methylpyrazolyl-IV-Enzima -> Pazufloxacin -> Fenitrothion -> Methidathion -> Orthene -> Fipronil-- > FENOTHIOCARB -> Phosmet -> amino-II-IV-V-METHYLSULFANYL, PYRIMIDINE, CARBOXYLICACID ETHYL ESTER -> Dimethylphosphorodithioate -> Dimethyl chlorothiophosphate -> ISOFENPHOS -> CYANOPHOS -> V-HYDROXYMETHYLCYTOSINE -> Azamethiphos -> A. (CVIII)CDLXXVII -> CARBOPHENOTHION -> amino-IV-2 '(METHYLTHIO) PYRIMIDINE-V-CARBOXYLICACID -> amino-IV-2' (METHYLTHIO) -6-PYRIMIDINOL -> Ranitidine hydrochloride-- > Aminoguanidinium sulphate -> Mifepristone -> V-CARBOXYCYTOSINE -> Methyl [(dimethoxyphosphinothioyl) Thio] acetate -> FLOSEQUINAN -> Procarbazone sodium -> Fluticasone propio -> Ammonium Domine, Domine, amino dithiophosphate-- > CHLOROMETHYL mETHYL sulfide -> METHYLTHIO-IV-II-IV-yl pentanone |