diethyl malonate

Product Name:

diethyl malonate

Synonym:

ACIDUM MALONIC diethyl ESTER: MALONIC ESTER: ETHYL malonate: Ethyl propanedioate: potenti MMCCCLXXV: DEM: DICARBETHOXYMETHANE: diethyl malonate

CAS:

105-53-3

MF:

C7H12O4

MW:

160.17

EINECS:

203-305-9

Product Categories:

Aedificium cuneos, ut c6 C7; Carbonyl Composita: Synthesis Donec; Fruit; Organics; Organici aedificium cuneos

Mol File:

105-53-3.mol

Liquescens punctum

-50 ° C

Ferveret

CXCIX ° C (Litt.)

density

1.055 g / ml ad XXV ° C (Litt.)

vapor densitatem,

5.52 (VS caeli)

vapor pressura

I mm Aggaei (XL ° C)

potenti

MMCCCLXXV | diethyl malonate

refractivam index

n20 / D 1.413 (lit.)

Fp

CCXII ° F

temp repono.

+ Copia infra XXX ° F.

solubility

20.8g / l (externi MSDS)

pka

13.5 (ad 25a)

forma

Liquid

terminus explosive

0.8-12.8% (V)

aqua Solubility

Miscible cum ethyl arcu, sive, et benzene chloroform. Miscibilia paululum aqua.

Number JECFA

614

Merck Poland

14,3823

BRN

774687

Stabilitatem:

Firmum. Combustibilis ab aere obscuritas. Simul acri oxidizing agentibus

InChIKey

IYXGSMUGOJNHAZ UHFFFAOYSA-N,

CAS DataBase Reference

105-53-3 (CAS DataBase Reference)

Quaestiones NIST Reference

Acidum Propanedioic, diethyl Esther (105-53-3)

Ratio Subcriptio quod substantia EPA

Diethyl malonate (105-53-3)

aleam Codes

XI

risk Denunciationes

XXXVI / XXXVII / 38-36

Denunciationes salutem

XXIV / 25-26

Germania WGK

1

RTECS

OO0700000

Autoignition Temperature

Signa (LI)DCCXCIV CDXXXV ° F

Nota aleam

Simplex

Capparis

Ita

HS Code

29171910

Aedes

LD50 viva apud CUNICULUS: (XV)DCCXX mg / kg LD50 dermal Materiae> (XVI) mg / kg

Properties eget

sine colore humor

Properties eget

Diethyl malonate est vestrum, iucundum, odori aromatico.

usibus

de ducens artifices et barbiturates.

Praeparatio

Acidum Acidum cyanoacetic chloroacetic reagens est per sodium cyanide, et subsequent saponificationis; Acidum malonic esterified tandem sit per destillationem in ethanol praeservatum azeotropic in benzene

Saporem limine values

Habet etiam: ppm L ad gustum, dulcis pineapple et pupillam fruity atque extenuatis proponuntur.

salutem Profile

Leviter toxicus per ingestion. A cutis irritationem. Carros sunt calidum et humidum, cum patere flamma; potest reflecti cum MORSUS materiae. Pugnare ignis aquas pallio utitur igne albet CO2 sicco eget. Acri nidore fumum emittit exagitandis calefacta corrumpi. Vide etiam esters.

Ratio purificatione

Quod si et impuros (IR, NMR) de Pascha (250g), altercatione orta est vapor balneum pro 36hours EtOH est absoluta (125ml) et H2SO4 conc (75ml), deinde per Legem: eliquatus fractionally reducta pressura. Sub pressione redigi fractionally aliter fluat decoqui aliumque mediam partem aequabilis. [Beilstein 1881. II, IV]

Praeparatio Products

HEXYLDECANOIC acid-II -> CYCLOPENTYLACETIC ACIDUM -> II-V-acid-Chloro, BENZOFURAN ETHYL ESTER -> Enoxacin -> Phenylbutazone -> Dichloro-4,6-2- (methylsulfonyl) IMP -> BENZOFURANCARBOXYLIC II-acid ETHYL ESTER -> NITROBENZOFURAN-II-V-acid -> chloro, II-IV-VI-METHANESULFONYL, yl, PYRIMIDINE -> diethyl chloromalonate -> ETHYL-II-VII-METHOXYBENZOFURAN carboxylate -> 5,7-bis (TRIFLUOROMETHYL) -4-CHLOROQUINOLINE -> II-Mercapto-4,6-dimethoxypyrimidine -> IV-VI-Chloro, yl, 2. (METHYLTHIO) IMP, XCVIII% -> 5,7-bis (TRIFLUOROMETHYL) -4-HYDROXYQUINOLINE -> 2. (TRIFLUOROMETHYL) -4-V-acid-HYDROXYPYRIMIDINE -> Nitropyridine-II-V-acid -> II-ethoxy acid-MALONIC diethyl ESTER -> Dihydroxypyrimidine-V-acid, 2,4 -> dihydroxy-4,6-II-methylpyrimidine -> 5,7-bis (TRIFLUOROMETHYL) -4-III-acid-HYDROXYQUINOLINE -> IV -Chloro-7 (trifluoromethyl) quinoline -> ETHYL chloro-IV-6 (TRIFLUOROMETHYL) -3-QUINOLINECARBOXYLATE ->-5,7-IV-hydroxy acid-III-bis-TRIFLUOROMETHYL, Quinolina ETHYL ESTER- -> TRIETHYL 1,1,2, ETHANETRICARBOXYLATE -> ETHYL 2. (ETHYLTHIO) -4-HYDROXYPYRIMIDINE-V-carboxylate -> 2,4,5 Trifluorophenylacetic, acidum -> Gliclazide -> II-IV-MERCAPTOPYRIMIDINE : VI-diol -> ETHYL-IV-6-hydroxy (TRIFLUOROMETHYL) Quinolina-III-carboxylate -> diethyl butylmalonate -> II-AMINODIETHYLMALONATE -> amino-II-IV-VI-chloropyrimidin (3H) nominibus profero -> III-CARBETHOXYUMBELIFERONE -> diethyl 2. (II-CYANOETHYL) malonate -> V-CARBETHOXYURACIL -> CARBETHOXY-II-III-PIPERIDONE -> Amino-II-IV-VI-hydroxypyrimidin (3H) - una: XCVII% -> Sulfamonomethoxine

et rudis materiae

Etanol -> Hydrochloric acidum -> Sulphuric acidum -> Natrii carbonas -> Natrium cyanide -> Malonic acidum -> Chloroacetic acidum -> acidum Chloroacetic sodium sal -> Cyanoacetic acidum -> Peroxosulphates hydrogenorthophosphate-- > MALONIC ACIDUM Peroxosulphates SALARIUM