Product Name: |
ácido |
Synonym: |
minor ratione, princeps puritatem Cinnamicacid Wang (at) kf-chem.com: CitricAcidGr (Monohydrate); CinnamonAcid: Benzenepropenoicacid; III-Phenylpropenoic: ácido, trans- (SH); ZIMTSAEURE ERG.B.6: Phenylacrylicacid |
CAS: |
621-82-9 |
MF: |
C9H8O2 |
MW: |
148.16 |
EINECS: |
210-708-3 |
Product Categories: |
|
Mol File: |
621-82-9.mol |
|
Liquescens punctum |
CXXXIII ° C (Litt.) |
Ferveret |
CCC Â ° C (lit.) |
density |
1.2475 |
potenti |
MMCCLXXXVIII | ácido |
refractivam index |
1.5049 (estimate) |
Fp |
> CCXXX ° F |
pka |
pK s (XXV °) 4,46 |
aqua Solubility |
511.2mg / Q (ºC XXV) |
Number JECFA |
657 |
Stabilitatem: |
Firmum. Combustible.Incompatible magnis oxidizing agentium. |
CAS DataBase Reference |
621-82-9 (CAS DataBase Reference) |
Quaestiones NIST Reference |
Propenoic acidum-II, III-phenyl- (621-82-9) |
Ratio Subcriptio quod substantia EPA |
Cinnamicacid (621-82-9) |
aleam Codes |
XI |
risk Denunciationes |
36/37/38 |
Denunciationes salutem |
26-36 |
Germania WGK |
1 |
RTECS |
GD7850000 |
Aedes |
LD50 (g / kg): apud 3.57orally redibant, > 5.0 dermally cuniculosae Celtiberiae (Letizia) |
Analysis content |
Verius specimen perpenderent 500mg de horis in sicciora terrae quae erat arida in III filledwith silica gel; adde 0.1mol / L hydrogenii. |
Aedes |
Gras (potenti). |
uti limitata |
Potenti (mg / kg) softdrinks XXXI; XL frigus potum, CUPPEDIAE XXX; XXXVI pistrino; X gum. |
Properties eget |
Videtur quod whitemonoclinic triangulum HKL, paulum cinnamomum, cum odorem suavitatis. Est solutum in ethanol praeservatum, methanolum, PETROLEUM aetherium chloroform; benzene facile solubiles, aetheris acetone, acetic acidum et olea et inextricabilis inwater disulfide ipsum. |
usibus |
1. Potest esse asraw materiae in in manufacturing de niensis praesul, andpharmaceuticals aromata. |
modum productio |
1. Potest beobtained cooperatores calefacit per reactionem, et inter benzyl sodiumacetate chloride. |
Properties eget |
Monoclinic crystallis |
Properties eget |
Ácido isalmost INODORUS cum ardenti gustum, dulcis et posteaquam animum convertit reminiscentof et persicum. |
Praeparatio |
Duo isomers, trans Cis- et existunt; interest enim CONDITIO in usum qui est trans-isomer; inaddition ad naturalem originem, a fontibus (incisus vaporavi habitationem), illud potest esse preparedas sequitur: (I) ex benzaldehyde, sodium anhydrous acetate et aceticanhydride coram pyridine (Perkini reactionem); (II) frombenzaldehyde et ethyl acetate (Claisen condensatione); (III) a benzaldehydeand acetylene chloride, (IV) per oxidatio benzylidene cum acetone sodiumhypochlorite. |
salutem Profile |
per venenum et intravenous intraperitoneal partibus. Et mediocri toxicus per ingestion. A cute irritamentum. Carros SAac. Quando tale incalescit coëunt corrumpi dulcis quidam et acri Fumus atque fumos eiicit. |
Synthesis eget |
LudwigClaisen Raynerius (1851a MCMXXX) Germanus chemicus, in quibus primum et esters aldehydes MDCCCXC thesynthesis ex aromatibus cinnamates per reagens. Notum est quod Thereaction Claisen densitate descendit. |
Ratio purificatione |
Acidum in crystallize * a benzene, CCL4, calidum aquam, aqua / EtOH (III: I) vocant caelum aqueum vel EtOH XX%. lauans in vacuo ad 60o. Vapor est volatile. [IX Beilstein 2002. iv] |
et rudis materiae |
Benzyl chloride -> Natrium acetate trihydrate -> Kalium Acetate -> Calcium hypochlorite -> trans-ácido -> Benzalacetone |
Praeparatio Products |
Dominus Phytophthora -> 2. [3. [Bis (I-methylethyl) amino] -1 phenylpropyl] -4-methylphenol -> l phenylalanine |