Product Name: |
I-II, Methyl butanol, |
Synonym: |
Methylbutanol, I-II, II-Methyl-n-butanol: methyln, butanol-II, III, yl us-butanol; alcohole amyl Active primaria; activeprimaryamylalcohol: alcool2, methylbutylique: CH3CH2CH (CH3) CH2OH |
CAS: |
137-32-6 |
MF: |
C5H12O |
MW: |
88.15 |
EINECS: |
205-289-9 |
Product Categories: |
Alcohols, C2 ut C6: dolor Composita: Alphabetical Listings; et Sapor Fragrances, M, N; pharmaceutical Intermediates; alcohole LaudaBQLig |
Mol File: |
137-32-6.mol |
|
Liquescens punctum |
LXX â € Â ° C (lit.) |
delta |
+ -0.1ï½ 0.1A ° (20a / D) (salsa) |
Ferveret |
CXXX ° F mmHg (lit.) |
density |
0,819 g / ml ad  ° C XX (lit.) |
vapor densitatem, |
III (vs caeli) |
vapor pressura |
III mm Aggaei (Â ° C XX) |
refractivam index |
n20 / D 1,411 |
potenti |
MMMCMXCVIII | (+/-) - METHYL-I-II-butanol |
Fp |
CX Â ° F |
temp repono. |
regio Flammables |
solubility |
aqua: slightlysoluble3.6g / a00g ad XXX ° F |
forma |
Liquid |
pka |
± 0,10 15,24 (Praedicta) |
color |
Sine colore flavo, leviter patet tovery |
PH |
VII (H2O) |
terminus explosive |
1.2-10.3% (V) |
aqua Solubility |
3.6 g / C ml (XXX ºC) |
Merck Poland |
14,6030 |
Number JECFA |
1199 |
BRN |
1718810 |
CAS DataBase Reference |
137-32-6 (CAS DataBase Reference) |
Quaestiones NIST Reference |
Butanol-I, II-methyl- (137-32-6) |
Ratio Subcriptio quod substantia EPA |
I-II, Methyl butanol, (137-32-6) |
aleam Codes |
xII |
risk Denunciationes |
10-20-37-66 |
Denunciationes salutem |
46-24 / XXV |
RIDADR |
MCV III IR / PG III |
Germania WGK |
3 |
RTECS |
EL5250000 |
Autoignition Temperature |
DCCXXV ° F |
Capparis |
Ita |
HazardClass |
3 |
PackingGroup |
III |
HS Code |
29051500 |
Ancipitia substantiae Data |
137-32-6 (Malo Periculosam substantias Indicium) |
Aedes |
LD50 viva voce inRabbit: (IV)CLXX mg / kg LD50 dermal Quantum MMCM mg / kg |
Properties eget |
sine colore flavo liquido patet tovery slighlty |
Properties eget |
Amyl alcohols (pentanols) ut octo isomers. Omnia sunt flammabiles, hyalinae fluidum, praeter isomer2,2- propanol amino-I, quae est solidum crystallinum. |
Properties eget |
(+ / A) I-II-yl butanolhas cocti, assum aroma fruity vel cum alcoholico undernotes. |
usibus |
Quasque menstruis organicsynthesis (introductio de amyl coetus active), unguenta, plasticizers, additives pro unguentis colores. |
definitio |
Activae et ipsum ex fusel oleum. Quod productum est synthetica tum racemic mixtisque dextroand eoque agit optically levorotatory componit. |
Praeparatio |
I-II, yl butene fromhydroboration paratus est. (A) I-II-Methyl butanol est solitaria, fusel oleum byfractional potest distillari |
productio modos |
I-II, yl butanol ethanol productionem et probabuntur multi autem ex fusel oleum. Isoamyl alcohols sunt sicut menstrua pro olea pinguia nisl ac ceris; in plastics industria in polyacrylonitrile nere; quam in fabricandis lacquers, chemicals, et in veneficiis. |
Aroma limine values |
Odor in limine caeli: deprehendatur ad 0,14 mg / m3, recognition ad 0.83 ad 1.7 mg / m3. |
aleam |
Andexplosion modicus ignis periculum. Toxicus per ingestion ardorem inspiratio et cutis effusio. |
salutem Profile |
Et mediocri byskin toxicus contactus intraperitoneal ac itinera. Mddly toxicus per ingestion. An oculus cutem et membranas mucosas irritamentum. Causa potest surditas, delirium, capitis, nausea et vomitus. Flammabiles liquidum, cum patere calor, flamma, oroxidizers. Quando calor et vapor in forma explosivae patere flame.Incompatible cum H2S3. Pugnare ignis, usus alcohol spumam, aestus, vaporis, drychemical. Acribus emittit fumum irritatingfumes calefacta corrumpi. Vide etiam alcohols. |
Potentialis expositio |
(Isomer-n): Suspecta reprotoxic aleam: Prima irritamentum (v / o allergic reactionem) (iso-, prima): Possibile periculo formatam secretiori parte natium: Prima irritamentum (v / o allergicreaction) (sec-, primary- activae, et alia isomers) prima irritamentum (v / oallergic reactionem). Uti organi nariae syntheticflavoring synthesis, veneficiis, pede inhibitors; Plastics otherchemicals et facere; ut flotation agente. Et (n-isomer) sit usus est in praeparationem oiladditives, plasticizers, synthetica unguenta, sicut et solvent. |
naviportans |
UN2811 Pentanols, Aleam classis III, Labels: 3 Flammabiles SAac. UN1987 alcohols, n.o.s. Hazard Class: III: Comments-Flammabiles III SAac. |
Ratio purificatione |
Et refluxus butanolwith Cao, fluat, cum magnesii et refluxus iterum fractionally oris eius. Stipis specimenque altus purificati a materia sit nactus idoneam fractionalcrystallisation post conversionem in Pascha, ut thetrinitrophthalate vel nitrophthalate-III. Operae pretium salis conversa est in thecinchonine acetone et recrystallised ex CHCl3 per addere sal pentane.The saponified est, extrahi per aetheres, et per sublimationem fractionally. [Michael et al. J V Res Lat data CDIII MCMLX, Beilstein I II 1666] |
incompatibilities |
Explosivemixture esse forms per aerem. Fortis et consectetuer oxidizers trisulfide maycause explosiones cum igne. Possunt acida magnis. Formans terram metallis consectetuer stringens reactionwith violentum est fomes felis. |
Vastum dispositioni |
Aut dissolvendum aut miscere, cum materia combustibilis ab aere obscuritas solutarum et incenderent in eget Incinerator instructus cum scrubber et afterburner. Omnes foederati, status, locali et Aliquam normas servandas. |
Praeparatio Products |
II-II, Methylbutyl methylbutyrate -> Methyl isovalerate |
et rudis materiae |
CIL fusel |