II-Heptanone

Product Name:

II-Heptanone

Synonym:

II-Oxoheptane1, Methylhexanal, II-Heptanone, XCVIII%, II-Heptanone, Methylpentyl ketone, II-Heptanone, pura, XCVIII%, II-Heptanone, XCVIII%, pura, II-Heptanone, XCVIII% 100ML, II-Heptanone, XCVIII% 1LT, yl, amyl cetone (French)

CAS:

110-43-0

MF:

C7H14O

MW:

114.19

EINECS:

203-767-1

Product Categories:

H. NMR Reference Signa, NMRStable Isotopes; Spectroscopy: Stabilis Isotopes; Carbon Mors LENTO-Boquilla cann, ACS et Reagent Romani Solvents; Suspendisse vitrum utres, NUTRICIUM Research: Phytochemicals per fragilis (Cibus / Spice / herb); ReagentPlus: ReagentPlus solvente Romani Products: Semi-Solvents requirat molem, Utres solvente, in Application solvente, solvente packaging Options: Solvents: Industrial / denique chemicals, HAlphabetic-G, H. -HTAnalytical signa: Alphabetical Listings; officinarum (Ginger)

Mol File:

110-43-0.mol

Liquescens punctum

-35 ° C

Ferveret

CXLIX ° F

density

0.82

vapor densitatem,

3.94 (vs caeli)

vapor pressura

2.14 mm Aggaei (XX ° C)

potenti

MMDXLIV | II-HEPTANONE

refractivam index

n20 / D 1.408 (lit.)

Fp

CVI ° F

temp repono.

regio Flammables

solubility

aqua: soluble4.21g / L ° C XX

forma

Liquid

color

patet hyalinae

terminus explosive

1.11-7.9% (V)

Odor Limen

0.0068ppm

aqua Solubility

4.3 g / L (XX ºC)

Number JECFA

283

Merck Poland

14,4663

BRN

1699063

Henrici de assidua legis

3,59 at XXXVII ° C (Headspace stabilis, GC Bylaite et al., MMIV)

patefacio fines

TLV, TWA CCXXXV mg / m3 (50ppm) (ACGIH), CDLXV mg / m3 (ppm C) (NIOSH). .

Stabilitatem:

Firmum. Flammable.Incompatible magnis oxidizing agentia fortis redigo agentia strongbases.

CAS DataBase Reference

110-43-0 (CAS DataBase Reference)

Quaestiones NIST Reference

II-Heptanone (110-43-0)

Ratio Subcriptio quod substantia EPA

II-Heptanone (110-43-0)

aleam Codes

xII

risk Denunciationes

22-38-40-48 / XX / 22-20 / 22-10

Denunciationes salutem

36-24 / XXV

RIDADR

UN Consilium MMDCCCX 6.1 / PG III

Germania WGK

2

RTECS

MJ5250000

Autoignition Temperature

DCCXXXIX ° F

Capparis

Ita

HazardClass

3

PackingGroup

III

HS Code

29141990

Ancipitia substantiae Data

110-43-0 (Malo Periculosam substantias Indicium)

Aedes

LD50 inRabbit viva voce, MDCLXX mg / kg LD50 dermal Quantum (X)CCCXXXII mg / kg

Description

Musa sapientum fixa est acharacteristic Heptanone-II, CONDITUS leviter odor2, Heptanone byoxidation paratus sit in yl, n amyl carbinol; etiam n-amyl propionic fromethyl butyl acetat aut acidum.

Properties eget

II-Heptanone afruity habet, CONDITUS, cinnamomum, Musa sapientum fixa, paulo CONDITUS odore.

Properties eget

sine colore humor

Properties eget

Yl amyl ketoneis patet de colore liquida leni, Musa sapientum fixa, ut odoris suavissimi componendum.

Spermatophyta

Musa sapientum fixa est in colore, quasi liquidwith odoris suavissimi componendum. Deprehendi potest ad eiusdem collationem sub unius CXL μg / kg (Penuaria et al., 1969a). Cometto-mu? Iz et al. (MM), vndique a nuntiavit nasi pungencythreshold concentratione circa CMXXXV est CXCV ppm. An odorthreshold 6.8 ppbv intentio certior factus ab Nagataand Yokota (MCMXC).

usibus

Fornitrocellulose lacquers solvente, synthetica CONDITIO, pigmentaria.

usibus

In usum methyl amyl ketoneis flavoringagent est, qui menstrui, et resinam proposuerunt in lacquers andsynthetic.

definitio

ChEBI: A dialkylketone cum yl pentyl et coetibus sicut alkyl.

Praeparatio

A n-oxidatio ofmethyl amyl carbinol; Acidum vel etiam ex ethyl butylacetate propionic amyl, n.

Aroma limine values

DEPREHENSIO: ppm to1.33 bilionem I; recognition: ppm 2,66 ad 3,73, notas odor 1.0%, cheesy ketonic, leviter viridi cerae, et fruity Musa sapientum fixa.

Saporem limine values

Ppm Tastecharacteristics ad XX: cheesy, fruity, Cocoes, viridis, cerae, cremeo, cum fungal cellario et fruity brunneis atque extenuatis proponuntur.

Communia

A patet colorlessliquid. CXXVI mico punctum F. Et paulo rarior aqua solutum inwater. Hinc aquae supernatet. Aer vaporibus fuerit gravior. 6.8 density lb / Saccharum gal.Used pro CONDITIO et in odoribus aevum.

Agrippina Minor aqua Aeris &

Flammabiles. Slightlysoluble in aqua.

Reactividad Profile

Acida-II Heptanone reactsexothermically cum multis et sedes ideologicas ad producendum flammabiles gasorum (exampla, H2). Sufficiet ad succendendum caloris cum unreacted portion.Reacts ut redigo agentia hydrides, alcali metallorum et fomes nitrides toproduce calorem felis. Quae cum isocyanates, aldehydes, cyanides, peroxides et anhydrides. Repugnat multis oxidizing agentsincluding acido nitrico, acido nitrico / hydrogenii peroxide mixtisque et perchloricacid. Sit peroxides formare [USCG, MCMXCIX].

aleam

Modicus ignis ab inspiratione risk.Toxic cutis irritationem oculis, narcotic campi magni.

salutem DISCRIMEN

Inspiratione potest causeheadache inedias nausea, vomitus, vertigine compunctionis remerguntur disturbedvision et ignaro. Cutis contactus modica potest facere yellicationem, verbo defatting et DERMATITIS. Insecta, ut faciam os tuum, et labia tua irritatio, gastro-intestinorum yellicationem, verbo nauseam, profluvio ventris cupido dormiendi ofconsciousness damnum, celeri pulsus infirma et, frigus, pallide complexionis.

salutem DISCRIMEN

Patefacio ut methylamyl ketone causedirritation et mucosae membranae sententiīs multōrum cīvium tomoderate congestionof pulmonis agantur, in test animalia Narcosis. A IV-hora a4000 nuditate ad caeli-ppmconcentration in torats letalis fuit, 1500a MM ppm rege produci irrita [I], qu Narcosis. Theconcentration ad whichit producit similia symptoms isnot hominibus innotescit.
De compositis oris toxicity de his actum est irritans ad cutem low.Its putandam humilis humilem tovery.
LD50 valorem, oris (mures): DCCXXX mg / kg.

ignis DISCRIMEN

Carros fluit mico punctum (clausa poculum) 39.9 ° C (F CII) (Open poculum) 48.9 ° C (F XII); vapordensity 3.9 (= I caeli) vapor ad XX torr pressura 2.6 ° C (F LXVIII); autoignitiontempera [I] turae CCCXCIII ° C (DCCXL ° F), ignem extinxit-agente â alcoholâ spumam; et aqua ad imbre potest coolbelow ejus mico punctum.
Yl amyl ketone forms est explosivae mixturam 1.1% de aere in range [at66 ° C (150.8 ° F) variantur] ad 7.9% [ad CXXI ​​° C (249.8 ° F) variantur] ex volumine. Potest reactexplosively magnis acida, alkalies et oxidizing agentium.

salutem Profile

Et mediocri toxicus byingestion. Ab inspiratione et cutis leviter toxicus contactus. A cutis irritationem. Aut cum liquentia Aflammable patere calor flammae; Pugna tecum agere posse oxidizing materials.To ignis uti spuma CO2 sicco eget. Quando tale incalescit coëunt corrumpi itemits acer fumo nasci noscantur. Vide etiam ketones.

fons

Identified of140 volatile sint unum sicut unguentum in usus gram processingplant, ut colligitur ex variis frixum bubulae, pullum, vitulinam products (Takeoka et al., MCMXCVI). Etiam constituent identified as a volatile dimisit a nova coffeebeans (Coffea canephora varietate Robusta et Rubiaceae) differentstages ad maturitatis (Olga et al., MCMXCVIII).

fatum environmental

Biological. Heukelekianand Rand (MCMLV) relatum de X-valorem de 0,50 g d BOD / g quae est 17,8% of theThOD valorem de 2,81 g / g.
Eget / Physical. Atkinsonet al. (MM) products de Gas-tempus studiis operam et motu, heptanone of2 reactionem O radicalis in me purificatum in aere ad XXV ° C et mmHg DCCXL. Arelative constant rate de 10-11 cm3 x 1,17 / · secwas moleculae Neque enim hoc reactionem. Identified a reactionem products GC fur est, et massa spectroscopio et tandem ionization atmosphaericam pressionem (withrespective molaris iaceat) formaldehyde, 0.38; acetaldehyde ego »0,05; propanal ego »0,05; Butanal, 0.07; pentanal, 0.09; et hypothetica pondus organicnitrates CLXXV.
II-Heptanone non hydrolyze quia non continet a hydrolyzablefunctional coetus. Mollibus ardet in aeris carbo carbonis monoxide releasing et ipsum dioxide.

naviportans

UN1110, n Amyl Methylketone Hazard classis III, Comments-Flammabiles III SAac.

Vastum dispositioni

Dissolve admisceat thematerial ex objecto combustibili solutarum et incenderent in incineratorequipped eget scrubber et cum afterburner. Omnes foederati, status localenvironmental normas servandas.

et rudis materiae

Aethylicus -> 36-40% calcium chloride solutio (1box 27kgs =) -> oleum Castanea -> II-Heptanol

Praeparatio Products

(R) - (-) - II, AMINOHEPTANE -> II-Heptanol -> II-Oct-enal