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Natural Gamma Terpinene Basic informationes

Descriptio sicut sapor medicamentis Synthesis References

Product nomen:	Natural Gamma Terpinene
Synonyma:	1,1-DIETHOXYETHANE, 1,1-DIETHOXYACETAL, ACETAL, ACETALDEHYDE Diethyl ACETAL; DIETHYL ACETAL, FEMA MMII, ETHYLIDEN Diethyl aether; Acetal ~ 1,1-Diethoxyethane
CAS;	105-57-7
MF:	C6H14O2
MW:	118.17
EINECS:	203-310-6
Categoria:	Pharmaceutical intermedia
Mol fasciculi:	105-57-7.mol

Natural Gamma Terpinene Chemical Properties

punctum liquescens	-100 °C
fervens	103 °C
density	0.831 g/mL at 25 °C(lit.)
vapor density	4.1 (vs. caeli);
vapor pressura	20 mm Hg ( 20 °C )
FEMA	2002 \| ACETAL
refractivus index	n20/D 1.379-1.383(lit.)
Fp	-6 °F
repono temp.	Leo (+4°C) + Flammabiles area
solubility	46g/l
forma	Liquid
color	Patet hyalina
explosive modum	1.6-10.4%(V)
Aqua Solubility	46 g/L (25 C)
JECFA Number	941
Merck	14,38
BRN	1098310
Stabilitas:	Stabulum. Magnopere fomes. Sit formare peroxides in repono. Test peroxides ante usum. Vapores cum aere mixtionem explosivam formare possunt et ad fontem pergere ignitio et fulguratio retorsit. Vapores per humum spargere et in humilitate colligere areis angustiis ( cloacas , basements , lacus).
InChIKey	DHKHKXVYLBGOIT-UHFFFAOYSA-N
CAS Reference	105-57-7 (CAS Reference)
NIST Chemia Reference	Ethane, 1,1-diethoxy-(105-57-7);
EPA Substantia Registry System	Diethyl acetalis (105-57-7)

Natural Gamma Terpinene Salutis Information

Periculum Codes	F, XI
Periculum Denunciationes	11-36/38
Salus Denunciationes	9-16-33
RIDADR	UN 1088 3/PG 2
WGK Germania	2
RTECS	AB280000
Autoignition Temperature	446 °F . 446 °F
TSCA	Ita
HazardClass	3
PackingGroup	II
HS Code	29110000
Ancipitia substantiae Data	105-57-7
Toxicity	LD50 viva voce in muribus: 4.57 g/kg (Smyth)

Natural Gamma Terpinene Ritus Ac Synthesis

Descriptio	Acetal (nomen plenum; Acetaldehyde diethyl acetal/1,1-Diethoxyethane) est major CONDITIO componentia decoctarum, praesertim cupae brasii et sherry. Acetaldehyde diethyl acetal dicitur quasi agens saporem ad fructum praebendum; nux, -orum, sapores ac cupae. Potest agere cum diketene formare ethyl 5-ethoxy-3-oxohexanoatum coram chloride titanii. Potest etiam esse glycosides acetales mixtae per transacetalationem synthesize solebant.
Synthesis	Acetaldehyde diethyl acetal obtineri potest per reactionem inter alcohole ethyl et acetaldehyde coram calcii anhydroi chloride.
Descriptio	Patet acetal est; sine colore, ac perquam flammabiles liquore suavi odore. The vapor est susceptivus ignis mico causare. Acetal est sensilis ad lucem ac; reposita, peroxides formare possunt. Revera relatum est autoxidationis susceptibilis et ergo in genere peroxidisable. Acetale repugnat cum validis agentibus oxidising et acida.
Chemical Properties	patet, hyalina liquid
Chemical Properties	Patet acetal est; hyalina, et perquam amabilis liquore dulci odore. Vapor ut faciam fl cinis fi re. Acetale est sensitivum ad lucem et reposita peroxidas formare potest. Nam relatum est autoxidationem suscipere et debere; ergo classificari ut peroxidizabile. Acetal repugnat fortis oxidizing agentium et acida.
Chemical Properties	Acetale, an aldehyde ; est limpidus, liquor volatilis cum odore suavi
Chemical Properties	Acetal.has.a. refrigerium, .jucundum, .fruity-green.odor
usus	Solvendo; in synthetica unguenta ut Aenean; in organicis synthesibus.
Definition	A genus organicum compositum ex additione alcohol ad aldehyde. Praeter unum Vocatus moleculae hemiacetal dat. Praeterea ad- cedit plenum acetale. Similia reactiones fiunt cum ketonibus ad hemiketalia et ketala producenda.
Praeparatio	From.ethyl.alcohol.and.acetaldehyde.in.the.presente.of.anhydrous.calcium.chloride.or.small.amounts.of.mineral. acida.(HCl).
Aroma limina values	Deprehensio:.4.to.42.ppb
General Description	Patet hyalina liquore suavi odore. Fervens 103-104°C. Flash point -5°F. Densum 0.831 g / cm3. Leviter solutum in aqua. Vapores aere graviores. Mediocriter toxicus et narcotus in concentratione alto.
Aer & aqua Reactiones	Magnopere fomes. Formae caloris sensitivae peroxides explosivae in contactu cum aere. leviter solutum in aqua.
Reactividad Profile	Acetal potest agere acriter cum agentibus oxidizing. Stabile in basi sed ab acidis dilutinibus facile resolutum. Formae caloris sensitivae peroxides explosivae in contactu cum aere. Exempla vetera nota est explodere cum ob formationem peroxide calefactam [Sax, 9th ed., 1996, p. 5].
Periculum salutis	Sit irritare tractus respiratorii superioris. Concentraciones principales agunt ut systema nervosum centrale depressant. Indicia expositionis includunt capitis, vertigines, dormitationem; dolor abdominis, nausea.
Periculum salutis	Mitis irritamentum to pellis et oculi; acuta toxicityof low order; SOMNIFICUS in altum concentratione; IV-hora exposita (IV) ppm letalis ad mures et oris LD50 valorem Mures enim 3500 mg/kg.
Periculum salutis	Patefacio ut acetal pungentibus oculis cutis gastro tractu, nausea, vomit- tes, et deiectio. In concentrationes altos, effectus narcoticos efficit acetales in operariis.
Ignis Discrimen	Valde fomes; mico puncto (poculo clauso) -21°C (-6°F); vapor densitas 4.1 (aer = 1), vapor gravior aere et aliquod spatium iter ad fontem ignitionis et micare retro; autoignitio temperatus 230°C (446°F); vapor formae explosive mixturae cum aere, LEL et UEL valores sunt 1.6% et 10,4% per volumen in aere; respectively (DOT Label: Flammabilis Liquid, UN 1088). .
salus Profile	Mediocriter toxicus by ingestion, inhalation, and intraperitoneal routes. A cutis et oculi irritamentum. A medicamentorum. Periculosum ignis aleam cum calori vel flammae obnoxia; potest agere fortiter oxidizing materiae. Formae calor-sensitivo explosivae peroxides in contactu cum aere. dum calefacta corrumpitur emittit acre fumum ac fumus. Vide etiam ETHER ET ALDEHYDES.
Potentialis expositio	Solvendo adhibetur; in unguentis syntheticis, ut Aenean, fucis, saporibus; in organicis summam.
Shipping	UN1088 Acetal, Discrimen Classis: 3; Labels: 3-Flammabilis liquor. UN1988 Aldehydes, flammabilis, toxicum, n.o.s., DISCRIMEN Classis: III; Labels: 3-Flammabilis liquor, 6.1-Poenous materiae, nomen Technical required
Purificationis Methodi	Arida acetal super Na ad alcoholos et H2O tollendos, et ad aldehydes polymerise, dein fractos fluat. Vel cum alkalino H2O2 40-45o tracta, ut aldehydes removeas, deinde NaCl saturate, separato, exsiccato K2CO3 et ab Na[Vogel J . defluente Chem Soc 616 1948]. [Beilstein 1 IV 3103.]
incompatibilities "	Aldehydes sunt saepe implicari in auto-condensatione vel polymerization profectae. haec motus exothermic sunt; saepe catalyzed ab acido. Aldehydes sunt libenter oxidized dare acida carboxylica. Flammabiles et / vel toxicus vapores sunt generatur compositum aldehydes cum azo, diazo compositum; dithiocarbamates, nitrides, et fortes agentium minuentes. Aldehydes potest agere cum aere primum acida peroxo da, ac demum acida carboxylica. haec motus autoxidationis a luce excitantur, catalyzed per salia transitus metalla, et sunt autocatalytica (catalysata per motus reactionis). Additio stabilimenta (facilis) ad portationes aldehydes retardans autoxidatio. Praesumitur explosivae peroxides in contactu cum aere formare et lucem. Stabilis electrica crimen cumulare et ignitionem facere potest vapores ejus.
vastum Dispositione	Dissolve vel miscere materia combustibili solvendo et incineratori chemica uri instructum cum afterburner et scrubber. Omnes foederati, status et loci normae environmentales servandae sunt.

Natural Gamma Terpinene Praeparatio Products Et Rudis Materiae

Praeparatio Products

(1R-cis) -3-(2,2-dibromoethenyl) -2,2-dimethylcyclopropane carboxylic acid-->n-butyl vinyl ether-->2,2-dibromo-2-cyanoacetamide-->Misoprostol-->WL 108477-->1R-trans- methylum caronaldehydatum--> chloroacetaldehyde diethyl. acetal-->4-Fluoro-3-phenoxybenzaldehyde-->Mecillinam-->Dirithromycin-->Phenylpropyl aldehyde-->3-Chloropropionaldehyde diethylacetal-->CIS-4-HEPTENAL-->TRANS-2-HEXENAL-->FEMA 3378

Rudis materiae

Potassium carbonas-->Calcium chloridum-->Acetaldehydes

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